Spectrometer Detector Self-Diagnostics Using Branched Spectral Lines

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Solution Overview

Problem

Existing methods for diagnosing the performance of detectors in analytical plasma spectrometers are limited by the need for external light sources, manual assembly/disassembly, and are prone to errors due to random noise and non-linearity issues.

Innovation Solution

A diagnostic testing method that utilizes the intensity relationship between branched spectral lines emitted by a source of line spectra, such as a plasma source, to perform diagnostic tests on the detector without the need for external light sources or manual disassembly.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If external light sources are used to test the detector, then the detector can be diagnosed, but the process requires manual assembly/disassembly and increases device complexity

Engineering Contradiction:
Improvedetector diagnostic precisionVSAvoidtesting system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The spectrometer uses its own plasma source and detector to perform self-diagnosis by measuring the intensity ratios of spectral lines from the plasma source, eliminating the need for external light sources and manual assembly/disassembly operations

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The plasma source serves dual functions: as the analytical light source for sample analysis and as the diagnostic light source for detector testing, reducing the need for separate testing equipment

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Measurement precision

If standard solutions are used to test the detector, then the detector response can be evaluated, but the method is time-consuming and prone to dilution errors

Engineering Contradiction:
Improvedetector response measurement accuracyVSAvoidtime for solution preparation
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The method replaces the mechanical process of preparing and handling standard solutions with an automated plasma-based diagnostic approach, eliminating manual solution preparation and associated errors

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The diagnostic method changes the test parameter from solution concentration (which varies with time and preparation) to plasma spectral line intensity ratios (which are stable and reproducible), eliminating dilution errors

Inventive Principle:
Principle #35Parameter changes

3Reliability

If standard solution concentrations change over time, then the solutions age, but this causes non-linearity in the detector response

Engineering Contradiction:
Improvedetector response linearityVSAvoidsolution stability duration
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The method changes from measuring solution concentration (which degrades over time) to measuring plasma spectral line intensity ratios (which remain stable), eliminating the time-dependent non-linearity issue

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The method converts the plasma source, which naturally produces variable spectral output, into a stable diagnostic tool by using intensity ratios of lines from the same source, turning potential variability into a controlled measurement reference

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Productivity

If random noise is present in the light source, then measurements are performed, but precision is limited to a few percent

Engineering Contradiction:
Improvemeasurement throughputVSAvoidsignal measurement precision
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The method uses the plasma source's own spectral output as a reference feedback mechanism, measuring intensity ratios that compensate for random noise and provide stable diagnostic information

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The method converts the plasma source's inherent spectral variability into a beneficial reference system by using intensity ratios of lines from the same source, which cancels out random noise effects

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method provides an efficient and precise diagnostic test for detectors, eliminating the need for external light sources and reducing errors associated with random noise and non-linearity, thereby improving fault diagnosis and maintenance processes.

Implementation Method 1

The spectrometer comprises a plasma source, a detector and a controller. The plasma source is configured to emit spectral lines from excited species.

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

The optical radiation from an ICP and LIP source was used to determine the spectral response of a spectrometer

Methodology Applied
Scientific EffectElectromagnetic radiation emission: Electromagnetic Induction

Data Source

PatentUS20250290799A1Diagnostic testing method for a spectrometer
Publication Date: 2025.09.18 THERMO FISHER SCI BREMEN
  • US20250290799A1 patent drawing
  • US20250290799A1 patent drawing
  • US20250290799A1 patent drawing

AI summary

A diagnostic testing method for a detector of a spectrometer. The spectrometer comprises a source of line spectra configured to emit at least one branched pair of spectral lines from an excited species. The method comprises performing a plurality of detector diagnostic measurements and diagnosing a detector operating condition. Each detector diagnostic measurement comprises measuring an intensity of a first spectral line emitted by an excited species of the source of line spectra using the detector, and measuring an intensity of a second spectral line emitted by the excited species of the source of line spectra using the detector. The first and second spectral lines emitted by the excited species of the source of line spectra form a branched pair of spectral lines, and the spectrometer is controlled to vary the intensity of the first and second spectral lines incident on the detector for the plurality of detector diagnostic measurements.