Liquid Laundry Detergent with Cleaning Booster Polymer

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Solution Overview

Problem

There is a need for liquid laundry detergent formulations that maintain primary cleaning performance while reducing surfactant loading and improving anti-redeposition performance, particularly for dust sebum and ground clay, amidst growing environmental sensitivity and rising material costs.

Innovation Solution

A liquid laundry detergent formulation comprising a liquid carrier, a cleaning surfactant, and a cleaning booster polymer with specific structural units of monoethylenically unsaturated carboxylic acid monomers and ethylenically unsaturated monomers, which enhances cleaning performance and anti-redeposition capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If surfactant loading is reduced to lower costs and improve environmental performance, then material costs and environmental impact improve, but primary cleaning performance deteriorates

Engineering Contradiction:
Improvesurfactant loadingVSAvoidprimary cleaning performance
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent introduces a cleaning booster polymer as an intermediary substance that works synergistically with reduced surfactant levels to maintain cleaning performance. The polymer, containing specific functional groups (carboxylic acid, hydroxyl, amine), acts as a mediator that enhances the effectiveness of the reduced surfactant quantity, thereby resolving the contradiction between lower surfactant loading and maintained cleaning efficacy

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite detergent system combining surfactants with a specifically designed cleaning booster polymer. This composite material approach allows the system to achieve cleaning performance comparable to or exceeding traditional high-surfactant formulations while using reduced surfactant quantities, thus resolving the contradiction between material quantity and performance

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If surfactant loading is reduced to improve environmental performance, then environmental sensitivity concerns are addressed, but primary cleaning performance deteriorates

Engineering Contradiction:
Improveenvironmental sensitivityVSAvoidprimary cleaning performance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The cleaning booster polymer serves as an intermediary that compensates for the reduced surfactant environment, maintaining cleaning effectiveness while the overall formulation uses environmentally friendlier, lower surfactant levels. The polymer's multifunctional structure enables it to bridge the gap between environmental constraints and cleaning performance requirements

Inventive Principle:
Principle #24Intermediary (Mediator)

3Quantity of substance

If polymer is added to reduce unit dose of surfactant, then surfactant utilization is reduced, but anti-redeposition performance may be insufficient

Engineering Contradiction:
Improveunit dose of surfactantVSAvoidanti-redeposition performance
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The cleaning booster polymer is designed with specific local functional qualities - carboxylic acid groups for cleaning action, hydroxyl groups for anti-redeposition, and amine groups for fabric interaction. This localized functional distribution within the polymer structure allows it to simultaneously address surfactant reduction and maintain anti-redeposition performance that simpler polymers cannot achieve

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulation improves primary cleaning for dust sebum and maintains good anti-redeposition performance for ground clay, achieving effective cleaning with reduced surfactant usage.

Implementation Method 1

a cleaning booster polymer, wherein the cleaning booster polymer, comprising: (a) 50 to 95 wt %, based on dry weight of the cleaning booster polymer, of structural units of a monoethylenically unsaturated carboxylic acid monomer; (b) 5 to 50 wt %, based on dry weight of the cleaning booster polymer, of structural units of an ethylenically unsaturated monomer of formula (I)

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12018234B2Liquid laundry detergent with cleaning booster
Publication Date: 2024.06.25 ROHM & HAAS CO
  • US12018234B2 patent drawing
  • US12018234B2 patent drawing
  • US12018234B2 patent drawing

AI summary

A liquid laundry detergent formulation is provided, comprising: a liquid carrier; a cleaning surfactant; and a cleaning booster polymer, wherein the cleaning booster polymer has structural units of a monoethylenically unsaturated carboxylic acid monomer; structural units of an ethylenically unsaturated monomer of formula (I)and,optionally, structural units of an ethylenically unsaturated monomer of formula (II)wherein x is an average of 0 to 20; wherein y is an average of 0 to 30; wherein x+y>1;wherein R1 is a —C1-4 alkyl group; and wherein R2 is selected from hydrogen and a methyl group.