Detergent Composition with Lipase and Shading Dyes

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Solution Overview

Problem

White fabrics tend to develop a yellowish tinge over time due to incomplete soil removal and sebum deposition, which existing detergent compositions with shading dyes and lipase do not effectively address, especially in multiple washes on cotton and polyester fabrics.

Innovation Solution

A detergent composition comprising a surfactant, hydrophobic dye, direct dye, acid dye, and lipase, which is applied in an aqueous solution to treat fabrics, followed by rinsing and drying, to reduce soil redeposition and maintain fabric whiteness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If shading dyes are used to mask yellowish tinge on white fabrics, then fabric whiteness is improved, but dye deposition is reduced when soil or sebum accumulates on fabrics

Engineering Contradiction:
Improvefabric whitenessVSAvoiddye deposition consistency
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent introduces lipase as an intermediary substance that mediates between the soil/sebum accumulation problem and the dye deposition requirement. The lipase enzyme breaks down triglycerides in sebum and oily soils into free fatty acids, monoglycerides, and diglycerides, creating a cleaner fabric surface that facilitates consistent dye deposition while maintaining fabric whiteness through the shading effect

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If lipase is used to enhance grease removal, then cleaning performance is improved, but malodour is generated due to hydrolysis of triglycerides

Engineering Contradiction:
Improvegrease removal efficiencyVSAvoidmalodour
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful malodorous volatile fatty acids produced by lipase action into a beneficial outcome. By combining lipase with shading dyes, the composition achieves enhanced grease removal while the shading dyes mask any potential yellowing, and the overall system promotes better fabric cleanliness and dye deposition, transforming the potential harm into an overall beneficial cleaning performance

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Productivity

If multiple washes are performed on white fabrics, then fabric cleanliness is maintained, but yellowing increases over time

Engineering Contradiction:
Improvewashing frequencyVSAvoidfabric brightness
Core Design Contradiction:
ProductivityVSIllumination intensity

Solution Approach 1:

The patent implements continuous useful action by combining lipase and shading dyes in a single detergent composition that works synergistically across multiple wash cycles. The lipase continuously breaks down greasy soils while the shading dyes continuously deposit to mask yellowing, creating an ongoing protective effect that maintains fabric brightness over extended use and multiple washes

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively reduces soil redeposition and yellowing, as evidenced by higher reflectance and lower yellowing indices on knitted cotton, knitted polyester, and polyester fabrics, especially after multiple washes.

Implementation Method 1

Lipase catalyses hydrolysis of triglycerides which form a major component of many commonly encountered fatty soils such as sebum, animal fats (e.g lard, ghee, butter) and vegetable oils

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

They absorb ultra violet light and emit visible light causing yellowed garments to look brighter. These dyes add a blue tint to fabrics, thereby masking the yellowish tinge

Methodology Applied
Scientific EffectAbsorption Spectroscopy: Absorption Spectroscopy

Implementation Method 3

They absorb ultra violet light and emit visible light causing yellowed garments to look brighter

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Data Source

PatentEP2635666B1A detergent composition having shading dyes and lipase
Publication Date: 2014.07.23 UNILEVER NV
  • EP2635666B1 patent drawing
  • EP2635666B1 patent drawing
  • EP2635666B1 patent drawing

AI summary

A detergent composition having shading dyes and lipase The invention relates to detergent compositions having shading dyes and lipase. It has been determined that combination of lipase with specific shading dyes provides lower redeposition of soil. This is manifested as higher reflectance and lower yellowing, especially over multiple washes on knitted cotton, knitted polyester and polyester fabrics, Disclosed is a detergent composition comprising: (i)a surfactant; (ii)a hydrophobic dye; (iii)a direct dye; (iv)an acid dye; and, (v)lipase.