Detergent Opacifying Agents for Stable Cloudy Appearance

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Solution Overview

Problem

The challenge lies in creating a detergent portion unit that is visually appealing, ecologically acceptable, and efficiently produced, particularly in achieving a stable cloudy-white appearance for white liquid detergents without using opacifying agents that are environmentally questionable.

Innovation Solution

A flowable detergent preparation containing 0.1-10% opacifying agents, 0.00001-1% colorants from red, blue, or violet groups, with a preferred use of inorganic divalent cation salts like magnesium and calcium salts, along with surfactants, fatty acids, and solvents, to maintain a stable cloudy-white appearance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If traditional organic opacifying agents are used to achieve a cloudy-white appearance, then the aesthetic quality is improved, but the ecological acceptability deteriorates

Engineering Contradiction:
Improvecloudy-white appearanceVSAvoidecological acceptability
Core Design Contradiction:
Illumination intensityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by replacing organic opacifying agents with inorganic divalent cation salts (calcium, magnesium). This parameter substitution maintains the desired cloudy-white appearance while eliminating the ecological harmfulness of organic additives, directly resolving the contradiction between aesthetic quality and ecological acceptability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs inexpensive inorganic salts that are naturally occurring and biodegradable. These divalent cation salts serve as temporary, non-persistent additives that provide the required optical properties without long-term environmental harm, replacing the more problematic organic opacifying agents.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-affected harmful factors

If inorganic divalent cation salts are used as opacifying agents, then the ecological acceptability is improved, but the stability of appearance over time may deteriorate

Engineering Contradiction:
Improveecological acceptabilityVSAvoidtime-stable appearance
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent creates a composite detergent system combining inorganic divalent cation salts with specific anionic and nonionic surfactants. This composite formulation ensures that the inorganic salts remain stable and effective over time, maintaining both ecological acceptability and appearance stability through the synergistic interaction of multiple components.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the concentration parameters of divalent cation salts within specific ranges (0.1-10% by weight) and combines them with controlled amounts of surfactants. This parameter optimization ensures that the inorganic salts maintain stable appearance properties over time while remaining ecologically acceptable, resolving the stability concern.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If highly concentrated detergent is used to reduce packaging volume, then the productivity is improved, but the ease of operation deteriorates

Engineering Contradiction:
ImproveconcentrationVSAvoidhandling
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent adjusts the rheological parameters of the detergent formulation by selecting specific surfactant types and their concentrations. This parameter adjustment ensures that even highly concentrated detergent maintains optimal flow properties and handling characteristics, resolving the contradiction between concentration and ease of operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses surfactants as intermediary substances that mediate between the high concentration requirement and the ease of operation requirement. The surfactants modify the physical properties of the concentrated detergent, enabling it to flow and handle easily despite the high concentration of active ingredients.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Manufacturing precision

If energy input is increased during mixing to achieve homogeneous distribution, then the manufacturing precision is improved, but the loss of energy increases

Engineering Contradiction:
Improvehomogeneous distributionVSAvoidenergy input
Core Design Contradiction:
Manufacturing precisionVSLoss of energy

Solution Approach 1:

The patent formulates a detergent system where the surfactants continuously stabilize the homogeneous distribution of ingredients during mixing. This continuous stabilization reduces the total energy input required, as the formulation maintains uniformity without requiring excessive mechanical energy, thus resolving the contradiction between manufacturing precision and energy loss.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution ensures a time-stable cloudy-white appearance and optimal viscosity, enhancing consumer appeal and processing simplicity while being ecologically friendly.

Implementation Method 1

the combination of these two ingredients ensures that the detergent preparation has a stable, cloudy-white appearance over time

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 2

at least one receiving chamber surrounded by a water-soluble film material

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentEP3943584A1Detergent portion unit with improved optical and rheological properties
Publication Date: 2022.01.26 HENKEL KGAA
  • EP3943584A1 patent drawing
  • EP3943584A1 patent drawing
  • EP3943584A1 patent drawing

AI summary

Free-flowing detergent preparation containing, based on its total weight, i) 0.1 to 10 wt.% of an opacifying agent; ii) 0.00001 to 1 wt.% of at least one colouring agent from the group of red, blue or violet colouring agents; process for its manufacture and washing process using these detergent preparations.