Unit Dose Detergent Pack Rigidity via Ethoxylated Fatty Acid

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Solution Overview

Problem

Unit dose detergent products with high solvent content face challenges in maintaining pack rigidity and integrity, leading to potential leakage or breakage, especially in multi-chamber designs, due to excessive weight distribution causing film overstretching and rupture.

Innovation Solution

Incorporating an ethoxylated fatty acid into the solvent system, which stabilizes the unit dose product and enhances pack rigidity, while maintaining high solvent content levels, using a solvent system comprising water and non-aqueous solvents like propylene glycol and glycerin, within a water-soluble or water-dispersible film container.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high solvent content is used in unit dose detergent formulations, then cleaning performance and efflorescence prevention are improved, but pack rigidity deteriorates causing sagging and floppy appearance

Engineering Contradiction:
Improvecleaning performanceVSAvoidpack rigidity
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent changes the chemical composition parameters of the solvent system by introducing ethoxylated fatty acid esters (with specific H/E ratios) and adjusting the proportions of glycerin, propylene glycol, and other solvents. This parameter optimization allows maintaining high total solvent content (30-70% by weight) while improving pack rigidity through enhanced solvent-solvent and solvent-film interactions.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If high solvent content is used in unit dose formulations, then efflorescence is prevented, but pack integrity deteriorates leading to rupture and leakage

Engineering Contradiction:
Improveefflorescence preventionVSAvoidpack integrity
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent creates a composite solvent system combining multiple components: water, glycerin, propylene glycol, and ethoxylated fatty acid esters. This composite formulation leverages the complementary properties of each component to achieve both efflorescence prevention and enhanced pack integrity through synergistic interactions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the concentration parameters of individual solvents within the total solvent system. By controlling the specific proportions of glycerin (5-30% by weight), propylene glycol (5-30% by weight), and ethoxylated fatty acid esters (10-40% by weight), the formulation achieves pack integrity while preventing efflorescence.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If high solvent content is used in multi-chamber unit dose products, then cleaning performance is maintained, but weight distribution causes sagging in lower chambers

Engineering Contradiction:
Improvecleaning performanceVSAvoidchamber weight distribution
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent modifies the density and viscosity parameters of the liquid composition by incorporating ethoxylated fatty acid esters with specific molecular weights and H/E ratios. This creates more uniform weight distribution across multi-chamber configurations, preventing sagging while maintaining cleaning performance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The inclusion of ethoxylated fatty acid stabilizes the unit dose product, preventing leakage and breakage, while maintaining cleaning performance and aesthetic appeal, even with high solvent content, and improves long-term pack rigidity.

Implementation Method 1

a container formed from a water-soluble or water-dispersible film material and a liquid composition being entrapped in the container

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Implementation Method 2

Glycerin and glycols (e.g., propylene glycol) are non-aqueous solvents, which are used in an amount sufficient to bind water, solvate materials, and fill volume within the detergent pack

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentEP3441446B1Unit dose detergent products with improved pac rigidity
Publication Date: 2021.04.28 HENKEL IP & HOLDING GMBH
  • EP3441446B1 patent drawing

AI summary

The present invention provides stable unit dose compositions with enhanced pack rigidity. Such unit dose compositions comprise water, at least one non-aqueous solvent, an ethoxylated fatty acid, a beneficial composition, and a water-soluble container formed from a water-soluble or water-dispersible film material.