Water-Soluble Detergent Pod Film Composition for Cold-Wash Dissolution

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Solution Overview

Problem

Existing water-soluble unit dose articles face issues with seal failures between films and incomplete dissolution during short and cold wash cycles, leading to structural integrity and dissolution profile problems.

Innovation Solution

A water-soluble unit dose article comprising a blend of polyvinyl alcohol homopolymer and anionic polyvinyl alcohol copolymer in the films, with a specific weight ratio and solvent sealing to ensure homogeneous sealing, reducing seal failures and enhancing dissolution under environmentally friendly wash conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a water-soluble film is used to provide structural integrity during storage and transport, then the film strength is improved, but the film may not dissolve adequately during short and cold wash cycles resulting in residue

Engineering Contradiction:
Improvefilm strengthVSAvoiddissolution reliability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies parameter changes by using polyvinyl alcohol with specific viscosity characteristics (4% solution viscosity between 8-12 mPa.s at 20°C) and controlled composition (less than 15% carboxylated anionic monomer units) to achieve both sufficient film strength and reliable dissolution under varied wash conditions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining polyvinyl alcohol homopolymer with carboxylated anionic monomer units in a controlled ratio to create a film that exhibits both mechanical strength and enhanced dissolution properties

Inventive Principle:
Principle #40Composite materials

2Strength

If the film is made stronger to prevent tearing, then structural integrity is improved, but seal failures may still occur due to stress concentration at seal locations

Engineering Contradiction:
Improvestructural integrityVSAvoidseal reliability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies local quality by using solvent sealing technology that creates localized strong bonds at the seal locations between film layers, concentrating the sealing action where needed while maintaining overall film strength and flexibility

Inventive Principle:
Principle #3Local quality

3Productivity

If a higher proportion of polyvinyl alcohol homopolymer is used to improve dissolution, then dissolution speed is improved, but film strength may be reduced

Engineering Contradiction:
Improvedissolution speedVSAvoidfilm strength
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent optimizes the parameter of polyvinyl alcohol composition by controlling the proportion of homopolymer (85-100%) and carboxylated anionic monomer units (<15%) to achieve the right balance between film strength and dissolution performance

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides reduced seal failures and maintains structural integrity while ensuring complete dissolution of the unit dose article, even under short and cold wash cycles.

Implementation Method 1

when the water-soluble unit dose article is added to water, the film dissolves/disintegrates releasing the internal contents into the surrounding water

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 2

seal the first and second water-soluble films together to create the water-soluble unit dose article

Methodology Applied
Scientific EffectSolvent sealing: Solvation

Data Source

PatentEP4015571B1Water-soluble unit dose article
Publication Date: 2026.04.29 PROCTER & GAMBLE CO
  • EP4015571B1 patent drawingFigure 1
  • EP4015571B1 patent drawingFigure 2

AI summary

Water-soluble unit dose article comprising a laundry or automatic dishwashing detergent and a method of making.