Detergent Surfactant Synergy for Low-Temp Drying

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Solution Overview

Problem

Existing automatic dishwashing detergents face challenges in achieving effective cleaning and drying performance, particularly in low-temperature cycles with reduced water consumption, where deposit formation and rinse aid efficiency are compromised.

Innovation Solution

A machine dishwashing detergent formulation incorporating a specific surfactant combination, including nonionic surfactants A and B, an anionic copolymer, builders such as carbonates and phosphates, and enzymes, which improves rinse and drying properties by optimizing surfactant ratios and polymer compositions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional automatic dishwashing detergents are used, then cleaning performance is achieved, but drying performance and deposit inhibition are insufficient, especially in low-temperature cycles

Engineering Contradiction:
Improvedrying performanceVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent combines multiple functions (cleaning, rinsing, drying, and deposit inhibition) into a single detergent formulation by integrating specific surfactant combinations (nonionic surfactant A with formula R1(OCH2CH3)n where n=5-20 and cationic surfactant B) that work synergistically to achieve all desired effects without requiring separate rinse aid products

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention uses composite surfactant systems combining nonionic and cationic surfactants with specific molecular structures and ratios to create a multifunctional detergent composition that provides both cleaning and drying performance, leveraging the complementary properties of different surfactant classes

Inventive Principle:
Principle #40Composite materials

2Reliability

If rinse aids are added separately to improve drying, then drying performance improves, but device complexity and packaging requirements increase

Engineering Contradiction:
Improvedrying performanceVSAvoidpackaging complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the rinse aid function into the main detergent formulation by incorporating cationic surfactant B in specific amounts (0.1-5% by weight), eliminating the need for separate rinse aid packaging and dosing systems while maintaining effective drying performance

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The detergent formulation achieves multiple functions (cleaning, rinsing, and drying) through a single product by using surfactant combinations that provide both洗涤 and anti-redeposition properties, making the detergent universally effective across all wash cycles without additional additives

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Loss of energy

If water consumption is reduced in cleaning cycles, then energy efficiency improves, but rinsing performance and deposit inhibition deteriorate

Engineering Contradiction:
Improveenergy efficiencyVSAvoidrinsing performance
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of the detergent by incorporating specific ratios of nonionic surfactant A (with ethoxylate chains of n=5-20) and cationic surfactant B, which change the surface properties of the rinse water to enhance drying and deposit inhibition even at reduced water volumes and low temperatures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates local quality improvements at the dish surface through targeted surfactant deposition, where the cationic surfactant B provides localized anti-redeposition and drying enhancement exactly where needed on the dish surface, maximizing effectiveness with minimal water consumption

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The detergent achieves enhanced cleaning and drying performance, reducing deposit formation and improving rinse efficiency, especially in low-temperature cycles, without the need for additional rinse aids or water softeners, thereby optimizing dishwashing processes.

Implementation Method 1

a) a nonionic surfactant A of the general formula R1(OCH2CH3)n, in which R1 is an alkyl radical with 12 to 22 carbon atoms and n is a number from 5 to 20

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 2

anionic copolymer from the group of polycarboxylic acids or polysulfonic acids

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP2358853B1Machine dishwasher detergent
Publication Date: 2017.02.08 HENKEL KGAA
  • EP2358853B1 patent drawing
  • EP2358853B1 patent drawing
  • EP2358853B1 patent drawing

AI summary

Machine dishwasher detergents comprising builder(s), enzyme(s), and a) a nonionic surfactant A of the general formula R1O(AlkO)xM(OAlk)yOR2 in which: R1 and R2 are each independently a branched or unbranched, saturated or unsaturated, optionally hydroxylated alkyl radial having 4 to 22 carbon atoms; Alk is a branched or unbranched alkyl radical having 2 to 4 carbon atoms; x and y are each independently values from 1 to 70; and M is an alkyl radical from the group of CH2, CHR3, CR3R4, CH2CHR3 and CHR3CHR4, where R3 and R4 are each independently a branched or unbranched, saturated or unsaturated alkyl radical having 1 to 18 carbon atoms, b) a nonionic surfactant B different than the nonionic surfactant A; c) an anionic copolymer C, are notable for an improved drying and rinsing outcome.