Deuterated Amine Compounds for OLED Hole Transport Efficiency

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Solution Overview

Problem

Existing organic electroluminescence display devices face challenges in achieving high luminous efficiency and long lifespan, particularly in the development of materials for hole transport regions that enhance charge transport properties and material stability.

Innovation Solution

The use of an amine compound represented by specific formulas, which includes deuterium substitution and specific structural configurations, is incorporated into the hole transport region of light-emitting elements to improve luminous efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional materials are used in the hole transport region, then the device structure remains simple, but the luminous efficiency and lifespan are insufficient

Engineering Contradiction:
ImprovelifespanVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by substituting hydrogen atoms with deuterium atoms in the amine compound structure. This isotopic substitution modifies the physical and chemical parameters of the material, resulting in enhanced stability and lifespan of the light-emitting element without fundamentally changing the device architecture

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining specific amine compounds with deuterium substitution into a coordinated hole transport material system. This composite approach creates a material with synergistic properties that simultaneously improve charge transport efficiency and material stability, resolving the contradiction between performance and complexity

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional hole transport materials are used, then the manufacturing process remains simple, but the charge transport properties are insufficient

Engineering Contradiction:
Improvecharge transport efficiencyVSAvoidmaterial synthesis complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The deuterium substitution in the amine compound represents a parameter change that enhances charge transport properties. The isotopic modification alters the vibrational frequencies and bonding characteristics, leading to improved charge mobility while maintaining compatibility with existing manufacturing processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by introducing deuterium substitution at specific positions within the amine compound structure (as defined in the chemical formulas). This localized modification optimizes charge transport properties at critical sites without requiring complete structural redesign, thus balancing performance improvement with manufacturing feasibility

Inventive Principle:
Principle #3Local quality

3Use of energy by moving object

If standard organic electroluminescence materials are used, then the device structure remains conventional, but the luminous efficiency is insufficient

Engineering Contradiction:
Improveluminous efficiencyVSAvoidmaterial composition complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent utilizes parameter changes through deuterium substitution to optimize the energy levels and electronic structure of the hole transport material. This modification enhances the efficiency of charge recombination and light emission processes, improving luminous efficiency while maintaining a relatively simple device structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The deuterium-substituted amine compound acts as an intermediary material that facilitates more efficient energy transfer between electrons and holes in the light-emitting layer. This intermediary role improves luminous efficiency by optimizing the charge transport and recombination processes without requiring fundamental changes to the overall device architecture

Inventive Principle:
Principle #24Intermediary (Mediator)

Data Source

PatentUS20250311620A1Light-emitting element, amine compound for the same, display device including the light-emitting element, and electronic apparatus including the display device
Publication Date: 2025.10.02 SAMSUNG DISPLAY CO LTD
  • US20250311620A1 patent drawing
  • US20250311620A1 patent drawing
  • US20250311620A1 patent drawing

AI summary

A light-emitting element includes a first electrode, a second electrode on the first electrode, a light-emitting layer between the first electrode and the second electrode, and a hole transport region between the first electrode and the light-emitting layer and including an amine compound represented by Formula 1: