Deuterated Anthracene Host OLED Emitter Structure

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Solution Overview

Problem

Organic light emitting diodes (OLEDs), particularly in blue pixels, face limitations in emitting efficiency and lifespan, which restrict the overall performance of organic light emitting display devices.

Innovation Solution

Incorporating a specific organic light emitting diode structure with a first emitting material layer containing a boron derivative dopant and an anthracene derivative host, along with an electron blocking layer and a hole blocking layer, to enhance the emitting efficiency and lifespan of OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional OLED structure is used in blue pixels, then device complexity is maintained at baseline, but emitting efficiency and lifespan are insufficient

Engineering Contradiction:
ImprovelifespanVSAvoidstructure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The emitting layer is segmented into multiple functional sub-layers: hole blocking layer, first emitting material layer with first dopant and first host, electron blocking layer, second emitting material layer with second dopant and second host, and third emitting material layer with third dopant and third host. Each sub-layer has specific materials and functions designed to optimize carrier blocking and emission characteristics, thereby extending device lifespan while maintaining manageable complexity through systematic functional division

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs composite material systems where each emitting material layer combines specific dopants (iridium complexes with defined ligand structures) and hosts (organometallic compounds with specific molecular frameworks). These composite materials provide synergistic effects that enhance emission efficiency and stability, contributing to improved reliability without excessive structural complexity

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional OLED structure is used in blue pixels, then manufacturing process is simplified, but emitting efficiency is insufficient

Engineering Contradiction:
Improveemitting efficiencyVSAvoidlayer structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

Different emitting material layers are assigned distinct local qualities with specific dopant-host combinations optimized for their respective positions in the device stack. The first emitting material layer uses specific iridium dopant and organometallic host, while subsequent layers use different combinations, creating localized optimization of emission characteristics that collectively enhances overall productivity

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent introduces a vertical dimensional arrangement of multiple emitting material layers with progressively different material compositions and functions. This multi-layer stacking in the vertical dimension allows for enhanced light extraction and emission control, improving emitting efficiency while organizing complexity in a structured spatial hierarchy

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Ease of operation

If conventional OLED structure is used, then device operation is simple, but color sense and power consumption performance are limited

Engineering Contradiction:
Improveoperation simplicityVSAvoidpower consumption
Core Design Contradiction:
Ease of operationVSUse of energy by moving object

Solution Approach 1:

The multi-layer emitting structure creates internal feedback mechanisms where hole blocking and electron blocking layers regulate carrier injection and recombination zones, optimizing electroluminescence efficiency. This self-regulating structure improves power consumption performance while maintaining straightforward device operation through inherent material property-based control

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed structure significantly improves the emitting efficiency and extends the lifespan of OLEDs, particularly in blue pixels, leading to better performance and reliability of organic light emitting display devices.

Implementation Method 1

The OLED emits light by injecting electrons from a cathode as an electron injection electrode and holes from an anode as a hole injection electrode into an emitting material layer (EML), combining the electrons with the holes, generating an exciton, and transforming the exciton from an excited state to a ground state

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20220216409A1Organic Light Emitting Device
Publication Date: 2022.07.07 LG DISPLAY CO LTD
  • US20220216409A1 patent drawing
  • US20220216409A1 patent drawing
  • US20220216409A1 patent drawing

AI summary

The present disclosure relates to an organic light emitting device that includes a substrate, and an organic light emitting diode positioned on the substrate and including a first electrode, a second electrode facing the first electrode, a first emitting material layer including a first dopant of a boron derivative and a first host of an anthracene derivative and positioned between the first and second electrodes, a first electron blocking layer including an electron blocking material and positioned between the first electrode and the first emitting material layer, and a first hole blocking layer including a hole blocking material and positioned between the second electrode and the first emitting material layer, wherein the first host is deuterated.