Deuterated Host Composition for Low-Voltage Organic EL Emission

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Solution Overview

Problem

Existing organic electroluminescence devices face challenges in maintaining the advantages of multiple materials used in combination, often leading to suboptimal performance, high drive voltage, and short device lifetime.

Innovation Solution

The use of a specific combination of two host materials, one of which contains deuterium, in the emitting layer of the organic electroluminescence device, comprising a cathode, anode, and an emitting layer with a dopant material, enhances device performance by reducing drive voltage and increasing external quantum efficiency while extending the device's lifetime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If two or more materials are used in combination in an organic layer, then the advantage of features of each material can be utilized, but the advantages are not necessarily maintained and performance may be deteriorated

Engineering Contradiction:
Improveutilization of material featuresVSAvoidperformance stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent applies parameter changes by incorporating deuterium atoms into the host material structure. This isotopic substitution modifies the physical and chemical parameters of the host material, leading to improved exciton management and reduced degradation while maintaining the benefits of multi-material combinations

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining deuterated host materials with specific dopant materials in the emitting layer. This composite approach allows the deuterated host to provide enhanced stability and exciton confinement, while the dopant materials contribute their specific optical and electrical properties, achieving both versatility and reliability

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional materials are used in the emitting layer, then the device can operate, but the drive voltage is high and the lifetime is short

Engineering Contradiction:
Improvedevice operationVSAvoiddevice lifetime
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The patent applies parameter changes through deuterium substitution in the host material structure. This isotopic modification changes the vibrational frequencies and binding energies, resulting in reduced non-radiative decay and improved device lifetime while maintaining operational reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the typically harmful effect of exciton-polaron interactions and material degradation into a benefit through deuterium substitution. The deuterated structure reduces degradation pathways and transforms exciton management into an advantageous mechanism for extended device lifetime

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If conventional materials are used in the emitting layer, then the device can operate, but the drive voltage is high

Engineering Contradiction:
Improvedevice operationVSAvoiddrive voltage
Core Design Contradiction:
ReliabilityVSPower

Solution Approach 1:

The patent applies parameter changes by using deuterium substitution to modify the energy levels and charge transport properties of the host material. This results in improved charge injection efficiency and reduced drive voltage while maintaining device operational reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The deuterated host material acts as an intermediary that facilitates efficient charge transport and exciton formation. It mediates between the electrodes and the dopant materials, improving charge injection and reducing the drive voltage required for device operation

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in an organic EL device with a low drive voltage, high external quantum efficiency, and a prolonged lifespan.

Implementation Method 1

When voltage is applied to an organic electroluminescence device (hereinafter, referred to as an organic EL device), holes and electrons are injected into an emitting layer from an anode and a cathode, respectively. Then, thus injected holes and electrons are recombined in the emitting layer, and excitons are formed therein.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP3998323B1Organic electroluminescent element and electronic device
Publication Date: 2025.11.12 IDEMITSU KOSAN CO LTD
  • EP3998323B1 patent drawingFigure 1
  • EP3998323B1 patent drawing
  • EP3998323B1 patent drawing

AI summary

An organic electroluminescence device, comrpising a cathode, an anode, and at least one emitting layer disposed between the cathode and the anode, wherein the emitting layer contains a first host material, a second host material, and a dopant material, wherein the first host material is a compound represented by the following formula (1), the second host material is a compound represented by the following formula (2), and one or more selected from the group consisting of the compound represented by the formula (1) and the compound represented by the formula (2) have at least one deuterium atom.