Two-Component Developer Carrier Coating for Environmental Stability

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Solution Overview

Problem

Two-component developers for electrophotographic systems face challenges in maintaining chargeability in high temperature and high humidity environments, where the resin coating on the carrier particles tends to detach, leading to a decrease in electric charge and reduced environmental stability.

Innovation Solution

A two-component developer is formulated with a carrier having a surface coated with a vinyl polymer resin that includes units with cycloalkyl or phenyl groups, which enhances the durability and moisture resistance of the resin coating, preventing detachment and maintaining charge stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a resin formed by polymerizing an alicyclic methacrylic acid ester is used for coating the carrier, then frictional chargeability and moisture resistance are improved, but the resin layer may detach from the core material particles after long-term use due to friction

Engineering Contradiction:
Improvemoisture resistanceVSAvoidadhesion strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent uses a composite resin coating formed by copolymerizing multiple monomers (alicyclic methacrylic acid ester, chain methacrylic acid ester, and crosslinking agent) to achieve both moisture resistance and adhesion strength. This composite material approach allows combining the beneficial properties of different resin components while mitigating their individual weaknesses.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters of the resin coating by introducing specific functional groups (carboxyl groups from methacrylic acid and crosslinking structures) to enhance both moisture resistance and adhesion. The crosslinking degree and functional group content are controlled to optimize the balance between detachment resistance and environmental stability.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a resin produced by copolymerizing a chain methacrylic acid ester with an alicyclic methacrylic acid ester is used to improve friction properties, then frictional chargeability is improved, but moisture resistance becomes inferior

Engineering Contradiction:
Improvefrictional chargeabilityVSAvoidmoisture sensitivity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent creates a composite resin system that combines chain methacrylic acid ester (for frictional chargeability) with alicyclic methacrylic acid ester and crosslinking agents (for moisture resistance). This composite formulation achieves both improved friction properties and enhanced moisture resistance simultaneously.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces specific functional groups (carboxyl groups from methacrylic acid) at specific locations in the resin structure to provide localized moisture resistance while maintaining the overall frictional chargeability properties of the copolymer system.

Inventive Principle:
Principle #3Local quality

3Duration of action of stationary object

If the resin coating is made more durable to prevent detachment, then long-term stability is improved, but chargeability in high temperature and high humidity environments decreases

Engineering Contradiction:
Improvelong-term stabilityVSAvoidchargeability stability
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent carefully controls the content of carboxyl groups and crosslinking degree in the resin coating to achieve optimal balance. The carboxyl group content is maintained within a specific range (0.1-5.0 mmol/g) to ensure both long-term stability and chargeability in high temperature and high humidity environments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a multi-component composite resin system where each component contributes specific properties: alicyclic methacrylic acid ester provides backbone stability, chain methacrylic acid ester provides chargeability, and crosslinking agents provide durability. The synergistic interaction of these components resolves the contradiction between long-term stability and chargeability stability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively suppresses the leakage of electric charge and maintains the amount of electric charge even in high temperature and high humidity conditions, enhancing the environmental stability of carrier charging performance.

Implementation Method 1

a carrier having a surface of a core material particle coated with a resin for coating, wherein the resin for coating is a vinyl polymer having a unit having at least a cycloalkyl group or a phenyl group

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

enhances the durability and moisture resistance of the resin coating, preventing detachment and maintaining charge stability

Methodology Applied
Scientific EffectMoisture resistance: Hydrophobe

Implementation Method 3

Functions required for a carrier include frictional chargeability appropriate to a toner

Methodology Applied
Scientific EffectFrictional chargeability: Triboelectric Effect

Data Source

PatentUS8785100B2Two-component developer
Publication Date: 2014.07.22 KONICA MINOLTA BUSINESS TECH INC
  • US8785100B2 patent drawing
  • US8785100B2 patent drawing
  • US8785100B2 patent drawing

AI summary

The present invention relates to a two-component developer which comprises a toner, and a carrier having a surface of a core material particle coated with a resin having a unit of general formula (1). The present invention provides a two-component developer which has enhanced environmental stability of carrier charging performance.