Electrostatic Image Developer Using Silica or Alumina Additives

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Solution Overview

Problem

Electrostatic charge image developers without titanium oxide face challenges in stabilizing charge amounts over time, leading to issues like deteriorated cleaning properties and image quality, especially in low-temperature and low-humidity environments.

Innovation Solution

Incorporating silica or alumina particles as external additives to the toner and carrier particles, with specific surface content ranges measured by XPS, to stabilize charge and improve image quality without using titanium oxide.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If titanium oxide is used as an external additive to stabilize charge amount, then charge stability is improved, but environmental compliance deteriorates

Engineering Contradiction:
Improvecharge stabilityVSAvoidenvironmental compliance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts titanium oxide from the external additive composition and replaces it with silica or alumina particles, thereby eliminating the environmentally problematic substance while maintaining the charge stabilization function through alternative materials

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the material parameters of the external additive from titanium oxide to silica or alumina with specific particle size ranges (0.1-10 μm), altering the chemical composition while preserving the functional properties needed for charge stability

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If titanium oxide is not used in the developer, then environmental compliance is improved, but charge amount stability deteriorates

Engineering Contradiction:
Improveenvironmental complianceVSAvoidcharge amount stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent introduces silica or alumina particles as intermediary substances that mediate between the toner and carrier, providing the necessary charge stabilization function without relying on titanium oxide, thus serving as a functional substitute that bridges the gap between environmental requirements and performance needs

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite external additive system combining silica or alumina particles with specific surface properties and particle size distributions, forming a composite material structure that achieves charge stability through synergistic effects of multiple components rather than a single substance

Inventive Principle:
Principle #40Composite materials

3Object-generated harmful factors

If carbon black or alumina is added to the carrier to lower resistance, then excessive charging is suppressed, but long-term charging stability deteriorates

Engineering Contradiction:
Improveexcessive chargingVSAvoidlong-term charging stability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent segments the charge control function between the external additives on toner particles and the coating resin layer on carrier particles, with silica or alumina providing primary charge stabilization and the coating layer providing secondary control, distributing the functional burden to achieve both immediate and long-term stability

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies a pre-formed coating resin layer containing metal oxide particles to the carrier particles before use, creating a preliminary protective and functional layer that prepares the carrier for long-term stable operation by pre-establishing the charge control mechanism on the carrier surface

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively maintains long-term charging stability and enhances image quality by suppressing excessive charge fluctuations and leakage, even in varying environmental conditions.

Implementation Method 1

the coating resin layer contains metal oxide particles... suppressing excessive charging at low temperature and low humidity

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

the toner particles contain at least silica particles or alumina particles as an external additive... stabilizing the charge amount

Methodology Applied
Scientific EffectElectrostatics: Electrostatics

Data Source

PatentUS10698329B2Electrostatic image developer
Publication Date: 2020.06.30 KONICA MINOLTA INC
  • US10698329B2 patent drawing

AI summary

Provided is an electrostatic charge image developer containing toner particles and carrier particles, wherein the toner particles contain at least silica particles or alumina particles as an external additive; the carrier particles contain core material particles and a coating resin layer covering a surface of the core particles; the coating resin layer contains metal oxide particles; an element measured by XPS (photoelectron spectroscopy) of the carrier particle is at least Si or Al; and a content of Si or Al in the carrier particle is in the range of 1 to 6 at % with respect to the total elements constituting the carrier particles.