Two-Component Developer Surfactant Charge Stability

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Solution Overview

Problem

In two-component developers used in electrophotographic apparatuses, the long-term use leads to degradation of toner chargeability and charge imparting properties due to abrasion and separation of external additives, resulting in insufficient toner charge and impaired image formation.

Innovation Solution

Incorporating toner particles with anionic surfactants and carrier particles with cationic surfactants, where the first resin particles have a zeta potential lower than 0 mV and the second resin particles have a zeta potential higher than 0 mV at pH 5, to maintain stable chargeability and prevent separation, ensuring continuous high-quality image formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If external additives are used to improve toner chargeability and carrier charge imparting property, then initial charge properties are enhanced, but long-term stability deteriorates due to abrasion and separation

Engineering Contradiction:
Improvecharge stabilityVSAvoidservice life
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The patent changes the chemical parameters of the toner and carrier surfaces by incorporating specific surfactants (anionic surfactant with higher negative chargeability than first resin particles, and cationic surfactant with higher positive chargeability than second resin particles). This creates strong electrostatic attraction between toner and carrier, stabilizing their charge properties during long-term use and preventing the degradation that normally occurs with external additive abrasion and separation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite structures by combining multiple components: toner mother particles with first resin particles and anionic surfactants, and carrier mother particles with second resin particles and cationic surfactants. This composite approach ensures that the toner and carrier maintain stable charge properties through strong electrostatic interaction, resolving the contradiction between initial charge performance and long-term stability.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional toner and carrier are used, then initial image formation is achieved, but replenishment fogging occurs during continuous printing

Engineering Contradiction:
Improvecontinuous printing capabilityVSAvoidimage quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the surface charge parameters of both toner and carrier by incorporating surfactants with higher chargeability than the resin particles. This creates a stable electrostatic interaction that prevents charge degradation during continuous printing, thereby eliminating replenishment fogging and maintaining image quality over extended printing operations.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If resin particles with low chargeability are used, then dispersion stability is improved, but toner chargeability and carrier charge imparting property decrease

Engineering Contradiction:
ImprovechargeabilityVSAvoiddispersion stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the chargeability parameter of the resin particles by coating them with surfactants that have higher chargeability (anionic surfactant on first resin particles, cationic surfactant on second resin particles). This enhances the electrostatic interaction between toner and carrier while maintaining dispersion stability through the surfactant layer, thereby resolving the contradiction between chargeability and stability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution ensures sustained positive chargeability of the toner and charge imparting property of the carrier, preventing replenishment fogging and allowing for continuous high-quality image formation by stabilizing the charge properties during long-term use.

Implementation Method 1

The first resin particles has a zeta potential lower than 0 mV at a pH of 5

Methodology Applied
Scientific EffectZeta potential: Electrostatics

Implementation Method 2

The second resin particles has a zeta potential higher than 0 mV at a pH of 5

Methodology Applied
Scientific EffectZeta potential: Electrostatics

Implementation Method 3

The toner is a positively chargeable toner that is positively charged by friction with the carrier

Methodology Applied
Scientific EffectTriboelectric charging: Triboelectric Effect

Data Source

PatentUS10067436B2Two-component developer
Publication Date: 2018.09.04 KYOCERA DOCUMENT SOLUTIONS INC
  • US10067436B2 patent drawing
  • US10067436B2 patent drawing

AI summary

A two-component developer includes a toner and a carrier. The toner is a positively chargeable toner that is positively charged by friction with the carrier. The toner includes a plurality of toner particles each including a toner mother particle and a plurality of first resin particles. An anionic surfactant having higher negative chargeability than the first resin particles is present on surfaces of the first resin particles. The carrier includes a plurality of carrier particles each including a carrier mother particle and a plurality of second resin particles. A cationic surfactant having higher positive chargeability than the second resin particles is present on surfaces of the second resin particles. The first resin particles have a zeta potential lower than 0 mV at a pH of 5. The second resin particles have a zeta potential higher than 0 mV at a pH of 5.