Electrostatic Charge Developer Toner Resin Fixing Temperature

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Solution Overview

Problem

The challenge is to reduce the fixing temperature of toner in image forming processes to lower energy consumption and enhance processing speed and productivity, while maintaining effective adhesion and charging properties.

Innovation Solution

An electrostatic charge developer is designed with a carrier having a resin coating layer containing a copolymer with nitrogen-containing acrylic esters and alicyclic acrylic esters, and a toner with a binder resin comprising non-crystalline and crystalline polyester resins, specifically using alkyl succinic acid or its anhydride, to achieve optimal glass transition temperatures and adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If the glass transition temperature of toner resin is lowered to reduce fixing temperature, then energy consumption is reduced, but adhesion properties may deteriorate

Engineering Contradiction:
Improvefixing temperatureVSAvoidadhesion
Core Design Contradiction:
TemperatureVSStrength

Solution Approach 1:

The patent employs composite materials by combining non-crystalline polyester resin (providing low glass transition temperature for low fixing temperature) with crystalline polyester resin (providing adhesion and mechanical strength). This composite approach allows the toner to achieve both low fixing temperature and good adhesion properties simultaneously, resolving the technical contradiction between these two parameters.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by carefully controlling the glass transition temperature of the non-crystalline polyester resin within a specific range (−50°C to 0°C) and the melting point of the crystalline polyester resin within a specific range (80°C to 120°C). By optimizing these parameters, the toner achieves both low fixing temperature and sufficient adhesion, resolving the contradiction between these opposing requirements.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If the glass transition temperature of toner resin is lowered to enhance processing speed, then productivity is improved, but charging properties may deteriorate

Engineering Contradiction:
Improveprocessing speedVSAvoidcharging properties
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent uses composite materials combining non-crystalline polyester resin (enhancing processing speed through low glass transition temperature) with crystalline polyester resin (maintaining charging properties through controlled melting point). This composite structure enables high productivity while preserving reliable charging properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by optimizing the glass transition temperature of the non-crystalline polyester resin (−50°C to 0°C) and the melting point of the crystalline polyester resin (80°C to 120°C). These parameter optimizations enable fast processing speed while maintaining stable charging properties, resolving the contradiction between productivity and reliability.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional polyester resins are used in toner, then manufacturing is simplified, but fixing temperature remains high increasing energy consumption

Engineering Contradiction:
Improvetoner manufacturingVSAvoidenergy consumption
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The patent applies parameter changes by selecting non-crystalline polyester resin with glass transition temperature in the range of −50°C to 0°C and crystalline polyester resin with melting point in the range of 80°C to 120°C. These parameter specifications enable low fixing temperature (reducing energy consumption) while maintaining ease of manufacture through the use of conventional polyester resin types.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining non-crystalline polyester resin (providing low glass transition temperature for energy-efficient fixing) with crystalline polyester resin (maintaining adhesion and charging properties). This composite approach achieves low energy consumption while keeping manufacturing processes simple and conventional.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution effectively lowers the fixing temperature, improves adhesion, and maintains charging properties, ensuring high productivity and energy efficiency in image forming processes.

Implementation Method 1

a carrier having a core material and a resin coating layer covering a surface of the core material, the resin coating layer containing a copolymer that contains (i) a nitrogen-containing acrylic ester or a nitrogen-containing methacrylic ester

Methodology Applied
Scientific EffectElectrostatic charging: Electrostatics

Implementation Method 2

the resin coating layer containing a copolymer that contains (i) a nitrogen-containing acrylic ester or a nitrogen-containing methacrylic ester and (ii) an alicyclic acrylic ester or alicyclic methacrylic ester

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

a toner containing a binder resin that contains a non-crystalline polyester resin and a crystalline polyester resin, the non-crystalline polyester resin containing at least (i) an alkyl succinic acid or an anhydride or lower alkyl ester thereof or (ii) an alkenyl succinic acid or an anhydride or lower alkyl ester thereof

Methodology Applied
Scientific EffectGlass transition: Phase Change

Implementation Method 4

the crystalline polyester resin being an aliphatic polyester resin

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS8142971B2Electrostatic charge developer, electrostatic charge image developer cartridge, process cartridge, and image forming apparatus
Publication Date: 2012.03.27 FUJIFILM BUSINESS INNOVATION CORP
  • US8142971B2 patent drawing
  • US8142971B2 patent drawing
  • US8142971B2 patent drawing

AI summary

An electrostatic charge developer includes a carrier having a core material and a resin coating layer covering the surface of the core material, and a toner having a binder resin that contains a non-crystalline polyester resin and a crystalline polyester resin. The resin coating layer contains a copolymer that contains a nitrogen-containing acrylic ester or nitrogen-containing methacrylic ester and an alicyclic acrylic ester or alicyclic methacrylic ester. The non-crystalline polyester resin contains at least an alkyl succinic acid or an anhydride or lower alkyl ester thereof, or an alkenyl succinic acid or an anhydride or lower alkyl ester thereof. The crystalline polyester resin is an aliphatic polyester resin.