Diamond-Particle Non-Stick Coating for Abrasion-Resistant Release

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Solution Overview

Problem

Existing non-stick coatings on metal substrates face challenges in achieving good adhesion, abrasion resistance, and wear resistance while maintaining effective food release, with previous solutions providing limited improvements in durability and wear resistance.

Innovation Solution

Incorporating diamond particles into the undercoat of a multilayer non-stick coating system, specifically in the midcoat, combined with ceramic particles and inorganic film hardeners, to enhance abrasion resistance and surface hardness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If fluoropolymer resins are used for non-stick coating, then release performance and chemical resistance are improved, but adhesion to metal substrate deteriorates

Engineering Contradiction:
Improverelease performanceVSAvoidadhesion to substrate
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The coating is divided into multiple functional layers: a fluoropolymer-based non-stick layer for release performance, and a separate undercoat layer containing diamond particles and ceramic fillers for adhesion and abrasion resistance. This segmentation allows each layer to optimize its specific function without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The undercoat combines diamond particles, ceramic fillers (such as aluminum oxide, silicon carbide), and binder resins to create a composite material that provides both strong adhesion to the metal substrate and high abrasion resistance, while the fluoropolymer layer provides the non-stick surface.

Inventive Principle:
Principle #40Composite materials

2Reliability

If large ceramic particles are incorporated to improve abrasion resistance, then wear resistance is improved, but coating uniformity and surface finish deteriorate

Engineering Contradiction:
Improveabrasion resistanceVSAvoidcoating uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

Large ceramic particles and diamond particles are concentrated in the undercoat layer where they provide abrasion resistance, while the overcoat fluoropolymer layer maintains a smooth, uniform surface for non-stick performance. Each layer has different compositional qualities suited to its specific function.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The undercoat layer can be designed with a porous structure that accommodates the ceramic particles and diamond particles, allowing them to be embedded within the matrix rather than creating surface irregularities. This porous structure also allows for better adhesion to the substrate.

Inventive Principle:
Principle #31Porous materials

3Reliability

If diamond particles are added to enhance hardness and abrasion resistance, then wear resistance is improved, but coating complexity and manufacturing difficulty increase

Engineering Contradiction:
Improvewear resistanceVSAvoidcoating system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

Diamond particles are incorporated specifically in the undercoat layer rather than throughout the entire coating system. This segmentation places the high-cost, high-performance material only where it is most needed for adhesion and abrasion resistance, while the fluoropolymer layers maintain simplicity and non-stick functionality.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The concentration of diamond particles can be optimized within the undercoat layer to achieve the desired level of abrasion resistance while controlling cost and processing complexity. Particle size distribution can also be adjusted to balance performance with manufacturing ease.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP1973672B1Non-stick coating composition comprising diamond particles and substrate having the composition applied thereto
Publication Date: 2013.06.12 DUPONT MITSUI FLUOROCHEMICALS CO LTD
  • EP1973672B1 patent drawing

AI summary

A non-stick coating composition comprising diamond particles of relatively large size, i.e., greater than 1 micrometer, preferably greater than 10 micrometers, and a fluoropolymer, can be applied to a substrate. In addition, a structure comprising a substrate and an undercoat is applied to the substrate, where the undercoat comprises a primer layer comprising a heat resistant non-fluoropolymer polymer binder and diamond particles, and optionally a midcoat also comprising diamond particles.