Boron-Doped Diamond Reflection Dynode for Charge-Stable Detection

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Solution Overview

Problem

Current electron emissive surfaces in detectors, such as those used in mass spectrometers, face limitations in secondary electron yield and charge accumulation under irradiation, leading to reduced detection efficiency and potential detector failure.

Innovation Solution

The use of a carbon-based layer, specifically diamond films doped with boron to enhance conductivity, as a reflection mode dynode in electron multiplication detection systems, which improves secondary electron emission and reduces charge accumulation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional electron emissive surfaces are used, then detector sensitivity is limited by low secondary electron yield, but using higher yield materials has not been successful in recent decades

Engineering Contradiction:
Improvedetection efficiencyVSAvoidsecondary electron yield
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the fundamental material parameter from traditional dynode materials to diamond material, which has inherently different electronic properties. This parameter change enables achieving high secondary electron yield that was not attainable with conventional materials, directly resolving the contradiction between detection efficiency and secondary electron yield

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs doped diamond, which is a composite material system combining diamond's structural properties with dopant-induced electrical properties. This composite approach enables the material to simultaneously achieve high secondary electron yield and controlled electrical characteristics, overcoming the limitations of traditional single-material dynodes

Inventive Principle:
Principle #40Composite materials

2Reliability

If electron emissive surfaces operate under higher irradiation levels, then detection sensitivity improves, but charge accumulation occurs leading to uncontrolled electrical potential changes and detector failure

Engineering Contradiction:
Improvedetection sensitivityVSAvoidcharge accumulation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent converts the harmful effect of charge accumulation into a beneficial property by utilizing diamond's wide bandgap and high breakdown voltage characteristics. These properties enable the diamond dynode to withstand high irradiation levels and manage charge accumulation effectively, transforming what was a failure mode into an operational advantage for high-sensitivity detection

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent changes the electrical parameters of the dynode material by using doped diamond, which provides controlled electrical conductivity and high breakdown voltage. This parameter change enables the surface to operate at higher irradiation levels without charge accumulation-induced failure, simultaneously improving detection sensitivity and preventing harmful charge buildup

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly enhances the sensitivity of electron multiplication detection systems by increasing secondary electron yield and preventing charge accumulation, thereby improving detection efficiency and extending the service life of detectors.

Implementation Method 1

the impact of a particle on a surface of the device causing the emission of one or more secondary electrons from the same surface

Methodology Applied
Scientific EffectSecondary electron emission: Photoelectric Effect

Implementation Method 2

diamond films doped with boron to enhance conductivity

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS12198915B2Reflection mode dynode
Publication Date: 2025.01.14 ADAPTAS SOLUTIONS PTY LTD
  • US12198915B2 patent drawing
  • US12198915B2 patent drawing
  • US12198915B2 patent drawing

AI summary

A device configured to convert or amplify a particle, the conversion or amplification being reliant on the impact of a particle on a surface of the device causing emission of one or more secondary electrons from the same surface. The device includes a carbon-based layer capable of secondary electron emission upon impact of a particle. The surface may be used to convert, for example, an ion into an electron signal, or an electron signal into an amplified electron signal, such as in conversion or amplification dynodes.