Diamond-Reinforced SiC Armor Tiles for Ballistic Impact

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Solution Overview

Problem

Current military personnel armor systems, particularly the ceramic tiles in hard armor components, face challenges in durability, mass efficiency, and effectiveness against aggressive ballistic threats like tool steel-tipped and armor-piercing projectiles, as they often undergo phase transformations under high pressure, leading to decreased ballistic performance.

Innovation Solution

The development of diamond-reinforced composite materials through a modified reaction bonding process, where diamond particulate is incorporated into the ceramic matrix with a protective carbonaceous coating to prevent chemical reaction with molten silicon, enhancing the hardness and resistance of the armor tiles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional ceramic tiles are used in hard armor, then the armor provides basic ballistic protection, but the ceramic undergoes phase transformations under high pressure from aggressive projectiles, leading to decreased durability and ballistic performance

Engineering Contradiction:
Improveballistic performanceVSAvoidphase transformation resistance
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent creates a composite material by incorporating diamond particulate (5-50 microns) into a reaction-bonded silicon carbide matrix. The diamond particles are protected by a carbonaceous coating that prevents chemical reaction with molten silicon during processing. This composite structure provides superior hardness and resistance to phase transformations under high-pressure ballistic impact compared to conventional monolithic ceramics.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the microstructural parameters of the ceramic by controlling diamond particle size (5-50 microns), concentration (1-20 volume percent), and the carbonaceous coating thickness. These parameter changes optimize the balance between hardness, toughness, and resistance to phase transformations while maintaining processability through reaction bonding.

Inventive Principle:
Principle #35Parameter changes

2Strength

If diamond particulate is added to enhance hardness and ballistic performance, then the armor resists aggressive projectiles better, but the diamond may chemically react with molten silicon during the reaction bonding process, degrading the diamond and reducing effectiveness

Engineering Contradiction:
ImprovehardnessVSAvoidchemical reaction with molten silicon
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent introduces a carbonaceous coating as an intermediary layer between the diamond particulate and the molten silicon matrix. This coating acts as a protective barrier that prevents direct chemical contact and reaction between diamond and silicon during the high-temperature reaction bonding process, thereby preserving the diamond's structural integrity and hardness-enhancing properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The carbonaceous coating is applied to diamond particles before they are incorporated into the ceramic matrix, providing preemptive protection against chemical reaction with molten silicon. This preliminary protective action prevents the harmful chemical interaction before it can occur during the reaction bonding process.

Inventive Principle:
Principle #9Preliminary anti-action

3Reliability

If the carbonaceous coating is applied to protect diamond particles, then chemical reaction with molten silicon is prevented, but the coating adds processing complexity and may affect the final microstructure and properties

Engineering Contradiction:
Improvediamond protectionVSAvoidprocessing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent utilizes the porous structure of the green body ceramic matrix to facilitate uniform distribution and attachment of the carbonaceous coating on diamond particles. The porosity allows the coating to penetrate and bond effectively, creating a robust protective layer without requiring excessive coating thickness or complex multi-step coating processes.

Inventive Principle:
Principle #31Porous materials

4Strength

If diamond concentration is increased to maximize hardness and ballistic performance, then the armor defeats more aggressive threats, but the material becomes more difficult to manufacture and may compromise microstructure uniformity

Engineering Contradiction:
ImprovehardnessVSAvoidmicrostructure uniformity
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent optimizes the diamond particle concentration parameter to a range of 1-20 volume percent, with preferred ranges of 5-15 volume percent. This parameter optimization ensures sufficient diamond content to enhance hardness and ballistic performance while maintaining uniform microstructure distribution and processability during reaction bonding. The specified diamond particle size range (5-50 microns) also contributes to uniform dispersion and avoids agglomeration issues.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The diamond-reinforced composite materials demonstrate improved durability, increased Young's modulus, and significantly enhanced ballistic performance, particularly against high-density WC/Co core projectiles, matching or exceeding the performance of commercial ceramics.

Implementation Method 1

diamond particulate is incorporated into the ceramic matrix with a protective carbonaceous coating to prevent chemical reaction with molten silicon

Methodology Applied
Scientific EffectChemical reaction prevention through protective coating: Coatings

Implementation Method 2

One may manufacture such a composite material by a metal infiltration process such as a silicon infiltration process such as a reaction bonding process

Methodology Applied
Scientific EffectMetal infiltration: Permeation

Data Source

PatentUS8474362B1Diamond-reinforced composite materials and articles, and methods for making same
Publication Date: 2013.07.02 II VI DELAWARE INC
  • US8474362B1 patent drawing
  • US8474362B1 patent drawing
  • US8474362B1 patent drawing

AI summary

A diamond-reinforced SiC ceramic composite material and shaped article. The addition of diamond to the microstructure greatly enhances properties such as hardness and Young's modulus. Such a composite material has considerable promise as an armor material. In particular, significant increases in ballistic performance can be achieved versus a non-diamond-containing composite, particularly versus the M993 threat. Reaction bonded silicon carbide (RBSC) ceramics with 7% diamond were shown to offer ballistic performance levels that matched the best commercial ceramics tested on the program.