Diamond Thin-Film Sensor Circuit for High-Sensitivity NV Center Detection

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Solution Overview

Problem

Current sensor systems utilizing NV centers in diamond for magnetic field detection have limited sensitivity and are difficult to miniaturize, restricting their application range and size reduction.

Innovation Solution

An integrated circuit with a diamond film containing NV centers and a microwave irradiation system, combined with a PIN diode structure and photoelectric conversion elements, enhances sensitivity and allows for miniaturization by improving NV center generation rates and detection methods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional diamond NV center generation methods are used, then the detection sensitivity is limited, but the manufacturing process is simpler

Engineering Contradiction:
Improvedetection sensitivityVSAvoidmanufacturing complexity
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters of the diamond film by incorporating boron atoms at specific concentrations (1×10^18 to 1×10^20 atoms/cm³) to enhance NV center generation. This parameter modification allows achieving higher detection sensitivity while maintaining manufacturability through controlled doping during chemical vapor deposition

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure by integrating diamond film with NV centers, boron-doped regions, and metal electrodes into a unified sensor system. This composite approach combines the advantages of diamond's wide bandgap with boron's ability to facilitate NV center formation, resolving the contradiction between sensitivity and manufacturing complexity

Inventive Principle:
Principle #40Composite materials

2Volume of moving object

If the sensor system size is reduced for wider application, then the application range increases, but the detection sensitivity decreases

Engineering Contradiction:
Improvesensor system sizeVSAvoiddetection sensitivity
Core Design Contradiction:
Volume of moving objectVSMeasurement precision

Solution Approach 1:

The patent applies local quality by concentrating NV centers in specific regions of the diamond film where detection is needed, rather than uniformly distributing them throughout a large volume. This allows miniaturization while maintaining high detection sensitivity in the critical sensing region through localized enhancement of quantum properties

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent transitions from bulk diamond sensing to thin-film diamond structures, moving the sensing functionality to a two-dimensional plane. This dimensional change enables significant size reduction while maintaining detection sensitivity through increased surface-to-volume ratio and enhanced optical access to NV centers

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Measurement precision

If the NV center generation rate is increased to enhance sensitivity, then the detection sensitivity improves, but the manufacturing precision requirements increase

Engineering Contradiction:
Improvedetection sensitivityVSAvoidNV center generation rate control
Core Design Contradiction:
Measurement precisionVSManufacturing precision

Solution Approach 1:

The patent implements feedback control during the chemical vapor deposition process by monitoring and adjusting parameters such as boron precursor flow rate, chamber pressure, and temperature to maintain optimal NV center generation rates. This feedback mechanism ensures consistent NV center production while managing manufacturing precision requirements

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent performs preliminary doping of the diamond film with boron atoms during the growth phase, before the actual sensing measurement. This preliminary action pre-establishes the conditions for high NV center generation rates, reducing the need for precise real-time control during operation and simplifying the manufacturing process

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly increases the detection sensitivity and reduces the size of the sensor system, enabling broader applications, including in living organisms and devices, by improving NV center generation rates and utilizing advanced detection techniques.

Implementation Method 1

a microwave irradiation system that irradiates the thin film with a microwave in response to driving from outside

Methodology Applied
Scientific EffectMicrowave radiation: Microwave Radiation

Implementation Method 2

an excitation unit that excites the electron included in the thin film in response to driving from outside

Methodology Applied
Scientific EffectElectron excitation:

Implementation Method 3

an intensity of light outputted from the thin film when the electron transitions from an excited state to a ground state

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 4

a change in conductivity of the thin film based on excitation

Methodology Applied
Scientific EffectElectrical conductivity change:

Implementation Method 5

the detection unit is a photoelectric conversion element that converts the light outputted from the thin film into an electric signal

Methodology Applied
Scientific EffectPhotoelectric conversion: Photoelectric Effect

Data Source

PatentUS11946879B2Integrated circuit and sensor system
Publication Date: 2024.04.02 TOKYO INST OF TECH
  • US11946879B2 patent drawing
  • US11946879B2 patent drawing
  • US11946879B2 patent drawing

AI summary

A thin film has a band gap of 2.2 eV or more and in which a crystal includes an atomic vacancy and an electron, a microwave irradiation system configured to irradiate the thin film with a microwave in response to driving from outside, an excitation unit configured to excite the electron included in the thin film in response to driving from outside, and a detector configured to detect, as an electric signal, at least either one of an intensity of light outputted from the thin film when the electron transitions from an excited state to a ground state and a change in conductivity of the thin film based on excitation.