Diamond Vacancy Defect Formation for High-Concentration NV Centers

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Solution Overview

Problem

Existing methods for forming nitrogen-vacancy centers in diamond do not efficiently increase the concentration of NV centers, which is crucial for improving the sensitivity of quantum sensors, as they lack temporal formation efficiency and yield.

Innovation Solution

A method involving the use of a pulsed laser to irradiate diamond with a fluence of 1.8 J·cm−2 or more in a focal region, with controlled focal region shape and size, and optionally under reduced pressure, to efficiently create vacancy defects and increase NV center concentration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a femtosecond laser is used to form NV centers in diamond, then NV centers can be formed in a desired pattern, but the temporal formation efficiency and yield do not increase

Engineering Contradiction:
Improvepattern precisionVSAvoidformation efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent changes the laser fluence parameter to 1.8 J/cm² or more, which is higher than conventional methods. This parameter change enables both high-concentration NV center formation and large-area processing, resolving the contradiction between precision and productivity by operating in an optimized parameter regime that achieves both goals simultaneously

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If the concentration of NV centers is increased to improve sensor sensitivity, then measurement sensitivity improves, but the existing methods lack temporal formation efficiency

Engineering Contradiction:
ImproveNV center concentrationVSAvoidformation speed
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent employs continuous irradiation with a femtosecond laser at optimized fluence to form high-concentration NV centers efficiently. The continuous action at the optimal fluence threshold enables sustained high-rate vacancy defect formation, achieving both high concentration and high formation speed without the temporal efficiency limitations of previous methods

Inventive Principle:
Principle #20Continuity of useful action

3Quantity of substance

If high fluence laser irradiation is applied to form vacancy defects, then NV center concentration increases, but graphitization may occur

Engineering Contradiction:
Improvevacancy defect concentrationVSAvoidgraphitization
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent uses pulsed femtosecond laser irradiation with specific pulse duration and repetition rate to deliver high fluence while allowing thermal relaxation between pulses. This periodic action enables accumulation of vacancy defects at high concentration without sustained thermal exposure that would cause graphitization, thus achieving high NV center concentration while avoiding the harmful thermal effects

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the efficient formation of high-concentration NV centers in a large region of diamond without graphitization, enhancing the sensitivity of quantum sensors and improving manufacturing productivity.

Implementation Method 1

concentrating pulsed light from a pulsed laser to irradiate the diamond with the pulsed light, wherein a fluence of the pulsed laser in a focal region on the diamond is 1.8 J·cm−2 or more

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Data Source

PatentUS20240410083A1Void defect forming method, device, and diamond manufacturing method
Publication Date: 2024.12.12 KYOTO UNIV
  • US20240410083A1 patent drawing
  • US20240410083A1 patent drawing
  • US20240410083A1 patent drawing

AI summary

Provided is a method for forming a vacancy defect in diamond, including the step of concentrating pulsed light from a pulsed laser to irradiate the diamond with the pulsed light, wherein the fluence of the pulsed laser in a focal region on the diamond is 1.8 J·cm−2 or more.