Diatomaceous Earth Purification Retaining Colloidal Structure

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Solution Overview

Problem

Existing methods for purifying diatomaceous earth for pharmaceutical use damage its natural structure, compromising its superior compressibility properties while achieving chemical purity, which is essential for bioavailability and stability of active ingredients.

Innovation Solution

A method involving acidic or oxidative treatment, separation, and controlled heating without calcination, using ultrasonic irradiation and specific acid and oxidizing agents, to maintain the natural colloidal structure and enhance chemical purity of diatomaceous earth.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If calcination is used to purify diatomaceous earth, then chemical purity is improved, but the natural colloidal structure is destroyed

Engineering Contradiction:
Improvechemical purityVSAvoidnatural colloidal structure
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent changes the temperature parameter from high-temperature calcination (900-1100°C) to low-temperature treatment (below 300°C), which allows purification while preserving the natural colloidal structure of diatomaceous earth. This parameter change resolves the contradiction by finding a temperature window that achieves sufficient purification without structural damage.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the thermal-mechanical calcination process with a chemical treatment process using acids and oxidizing agents. This substitution allows purification through chemical reactions rather than thermal decomposition, thereby preserving the physical structure while achieving the desired chemical purity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Object-generated harmful factors

If high temperature heat treatment is applied, then volatile impurities are removed, but the pore structure is damaged

Engineering Contradiction:
Improvevolatile impuritiesVSAvoidpore structure
Core Design Contradiction:
Object-generated harmful factorsVSShape

Solution Approach 1:

The patent changes the temperature parameter from high-temperature heat treatment to low-temperature treatment combined with chemical agents. This allows removal of impurities through chemical reactions at temperatures that do not compromise the pore structure integrity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces acid and oxidizing agent intermediaries that facilitate impurity removal at low temperatures. These chemical intermediaries enable the removal of volatile and non-volatile impurities without requiring high temperatures that would damage the pore structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If traditional purification methods are used, then chemical purity is achieved, but compressibility properties deteriorate

Engineering Contradiction:
Improvechemical purityVSAvoidcompressibility properties
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent changes the processing temperature parameter to below 300°C, which preserves the compressibility properties of diatomaceous earth while still achieving adequate chemical purity through the use of acid and oxidizing agent treatments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces high-temperature thermal processing with chemical processing using acids and oxidizing agents. This substitution achieves purification without the mechanical stress and thermal damage that would compromise compressibility properties.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Retains the natural structure and achieves higher chemical purity than traditional methods, ensuring superior compressibility and purity suitable for pharmaceutical applications.

Implementation Method 1

separating diatomaceous earth from said suspension optionally by applying ultrasonic irradiation

Methodology Applied
Scientific EffectUltrasonic irradiation: Ultrasound

Implementation Method 2

treating the separated diatomaceous earth with an organic or inorganic acid optionally by applying simultaneous ultrasonic irradiation

Methodology Applied
Scientific EffectAcoustic cavitation: Acoustic Cavitation

Implementation Method 3

treating the separated diatomaceous earth with an organic or inorganic acid

Methodology Applied
Scientific EffectAcid dissolution: Chemical Bonding

Implementation Method 4

purifying the heat-treated diatomaceous earth by oxidative treatment

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 5

heating the thus obtained diatomaceous earth at a temperature not higher than 300°C

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 6

drying the purified diatomaceous earth product

Methodology Applied
Scientific EffectDesorption: Desorption

Data Source

PatentEP2627606B1Method for purifying diatomaceous earth suitable for pharmaceutical use
Publication Date: 2016.08.31 ONP HLDG SE

AI summary

The present invention is related to a method for purifying diatomaceous earth wherein the natural colloidal structure of the material is retained, which comprises preparing a suspension of diatomaceous earth in a liquid wherein diatomaceous earth is insoluble, separating diatomaceous earth from the suspension, treating diatomaceous earth with an inorganic or organic acid, heat-treating the thus obtained product at a temperature not higher than 300°C, subjecting the product obtained to oxidative treatment and drying the purified product. The invention also relates to a product obtainable by the above-mentioned method.