Dichroic Dye Polarizing Layer for Heat Moisture Resistance

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Solution Overview

Problem

Current polarizing elements, such as those using iodine-polyvinyl alcohol films, suffer from poor durability, mechanical strength, and polarization characteristics due to heat and moisture sensitivity, leading to defects and cracks, which deteriorate their performance over time.

Innovation Solution

A novel dichroic dye compound with a high dichroic ratio and excellent physical/chemical stability is developed, along with a composition including this dye compound and a liquid crystalline compound, which forms a polarizing layer with improved polarization degree and durability when used in a display device.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If iodine-polyvinyl alcohol films are used in polarizing elements, then the polarizing element can be manufactured with existing processes, but the durability and mechanical strength deteriorate due to heat and moisture sensitivity

Engineering Contradiction:
ImprovemanufacturabilityVSAvoiddurability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters by replacing iodine with novel dichroic dye compounds having specific molecular structures (Formula 1 with defined substituents R1-R5, X1-X2, X1'-X2'). This parameter change maintains manufacturability through existing coating processes while dramatically improving durability and heat/moisture resistance of the polarizing element

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system by combining the novel dichroic dye compound with polyvinyl alcohol base material. This composite approach preserves the processability of polyvinyl alcohol while enhancing the overall reliability and mechanical strength through the superior thermal and moisture stability of the dichroic dye compound

Inventive Principle:
Principle #40Composite materials

2Device complexity

If conventional dye compounds are used in polarizing elements, then the manufacturing process remains simple, but the polarization characteristics and display quality deteriorate over time

Engineering Contradiction:
Improvemanufacturing process complexityVSAvoidpolarization characteristics
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent modifies the molecular structure parameters of the dye compound by introducing specific heteroatom-containing rings (HAr in Formula 1) with defined substituent patterns. This structural parameter change enhances polarization characteristics and long-term stability without complicating the manufacturing process, as the compound can still be applied using conventional coating and heating methods

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If polarizing elements are exposed to heat and moisture environments, then the operational conditions remain normal, but defects and cracks occur leading to performance deterioration

Engineering Contradiction:
Improveoperational conditionsVSAvoidheat and moisture sensitivity
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent replaces the thermally unstable iodine component with a more stable dichroic dye compound that does not require the same level of protective encapsulation. This substitution allows the polarizing element to withstand heat and moisture environments without developing defects or cracks, maintaining performance under normal operational conditions

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The novel dichroic dye compound creates a more chemically inert environment within the polarizing element structure, resisting degradation from moisture and heat. The stable molecular structure of the dye compound prevents harmful interactions with environmental factors, eliminating the need for additional protective measures against heat and moisture damage

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The novel dichroic dye compound and composition enhance the reliability and display quality of display devices by providing a polarizing layer with excellent polarization properties and stability, resistant to environmental factors like heat and moisture.

Implementation Method 1

A novel dichroic dye compound having a high dichroic ratio and excellent durability

Methodology Applied
Scientific EffectDichroism: Dichroic Filter

Implementation Method 2

a liquid crystalline compound; and a dye compound

Methodology Applied
Scientific EffectLiquid crystal phase transition: Liquid Crystals

Data Source

PatentUS10442931B2Dye compound, composition comprising dye compound, and display device using dye compound
Publication Date: 2019.10.15 SAMSUNG DISPLAY CO LTD
  • US10442931B2 patent drawing
  • US10442931B2 patent drawing
  • US10442931B2 patent drawing

AI summary

Provided are a dye compound, a composition comprising the dye compound, and a display device using the dye compound. The dye compound is represented by Formula 1.