Dichromatic Dye Composition for High-Contrast Guest-Host Displays

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Solution Overview

Problem

Current dichromatic dyes in guest-host liquid crystal compositions have high transmittance and nonuniform transmittance curves, making it difficult to achieve effective black color display and high contrast in liquid crystal devices.

Innovation Solution

A dichromatic dye composition with specific formulations of compounds (I), (II), and (III) is developed, providing high order parameter and miscibility, resulting in uniform absorption across 420-680 nm wavelengths, thus enhancing display contrast and solubility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the concentration of dichromatic dye is increased to improve absorption uniformity and black color display, then the absorption uniformity improves, but the light emission display capability deteriorates

Engineering Contradiction:
Improveabsorption uniformityVSAvoidlight emission
Core Design Contradiction:
Manufacturing precisionVSIllumination intensity

Solution Approach 1:

The patent divides the single dichromatic dye into a composition of multiple dichromatic dyes with different absorption characteristics. This segmentation allows each dye component to contribute to specific wavelength ranges, achieving uniform absorption across 420-680 nm without requiring excessive total concentration, thus maintaining light emission capability while improving absorption uniformity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the concentration parameters of individual dye components within the composition rather than increasing the total dye concentration. By optimizing the concentration ratios of different dichromatic dyes (Formula I, II, III), the patent achieves uniform absorption characteristics while keeping the total dye concentration at levels that preserve light emission display capability.

Inventive Principle:
Principle #35Parameter changes

2Device complexity

If a single dichromatic dye is used to simplify the system, then the system complexity is reduced, but the absorption uniformity across visible light spectrum deteriorates

Engineering Contradiction:
Improvedye composition complexityVSAvoidabsorption uniformity
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent combines multiple dichromatic dyes with complementary absorption characteristics into a single integrated composition. This merging approach achieves uniform absorption across the visible spectrum (420-680 nm) that cannot be obtained with a single dye, while the dyes are formulated to work synergistically rather than additively.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent creates a composite dichromatic dye composition consisting of multiple dye compounds (Formula I, II, III) with different absorption profiles. This composite material approach allows the combination of individual dye strengths to achieve superior overall absorption uniformity across the visible light spectrum.

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If dichromatic dye composition is optimized for uniform absorption, then the display contrast improves, but the solubility in host liquid crystal deteriorates

Engineering Contradiction:
Improvedisplay contrastVSAvoidsolubility
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The patent applies local quality by giving each dye component in the composition specific molecular structure characteristics that enhance solubility. Each dichromatic dye (Formula I, II, III) contains specific substituent groups and molecular arrangements that improve compatibility with the host liquid crystal, ensuring uniform distribution while maintaining the concentration levels needed for high display contrast.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The dichromatic dye composition achieves low transmittance and high solubility, enabling high-contrast black color display in liquid crystal elements by uniformly absorbing light across the 420-680 nm range, improving display quality and stability.

Implementation Method 1

Due to the dichroism (also known as absorption anisotropy, i.e. different absorbances are shown to polarized light perpendicular to or parallel to the absorption axis of the dichromatic dye) derived from the dichromatic dye

Methodology Applied
Scientific EffectDichroism: Pleochroism

Data Source

PatentUS9382480B2Dichromatic dye composition and application thereof
Publication Date: 2016.07.05 JIANGSU HECHENG DISPLAY TECH CO LTD
  • US9382480B2 patent drawing
  • US9382480B2 patent drawing
  • US9382480B2 patent drawing

AI summary

A dichromatic dye composition which has the characteristics of higher order parameter and good miscibility can be applied in a guest-host liquid crystal composition. The absorbance curve of a guest-host liquid crystal composition with the dichromatic dye composition within the range of 420-680 nm has the following characteristics: a. 2≦(T1+T2)/ΔT≦10; b. |T1−T2|≦0.5; c. 0<ΔT≦0.2, where T1 is a difference between a transmittance to light at 420 nm and a minimum transmittance, T2 is a difference between the transmittance at a wavelength of 680 nm and a minimum transmittance, and ΔT is a difference between the maximum and minimum transmittances on the transmittance curve within the wavelength range of 420-680 nm. A liquid crystal element with the guest-host liquid crystal composition provides a high-contrast display. A liquid crystal display device has the guest-host liquid crystal composition with the dichromatic dye composition.