Thermally Conductive Die Attach Film for Low-Temperature Void-Free Curing

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Solution Overview

Problem

Conventional film-like adhesives face challenges in curing at lower temperatures, leading to insufficient void discharge between the adhesive and the wiring board, which affects the thermal conductivity and reliability of semiconductor packages.

Innovation Solution

A thermally conductive film-like adhesive with specific compositions and properties, including an epoxy resin, epoxy resin curing agent, polymer component, and inorganic filler, is developed to achieve efficient curing at lower temperatures, ensuring effective void discharge and enhanced thermal conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If the film-like adhesive is highly filled with thermally conductive filler having small particle diameter, then thermal conductivity is improved, but fluidity decreases and voids are generated at interface

Engineering Contradiction:
Improvethermal conductivityVSAvoidinterface quality (void generation)
Core Design Contradiction:
TemperatureVSManufacturing precision

Solution Approach 1:

The patent changes the particle size parameter of the thermally conductive filler from small particle diameter to large particle diameter (d50: 3.0-10.0 μm). This parameter change resolves the contradiction by improving fluidity and reducing void generation while maintaining adequate thermal conductivity through optimized filler content (40-70 wt%).

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite adhesive composition combining epoxy resin, polymer component, and large particle thermally conductive filler with specific surface treatments. This composite approach allows the filler particles to disperse uniformly without aggregating, maintaining both fluidity for void-free bonding and thermal conductivity for heat dissipation.

Inventive Principle:
Principle #40Composite materials

2Use of energy by stationary object

If curing temperature is reduced, then energy consumption and damage to semiconductor package are reduced, but void discharge becomes insufficient

Engineering Contradiction:
Improvecuring energy consumptionVSAvoidvoid discharge efficiency
Core Design Contradiction:
Use of energy by stationary objectVSReliability

Solution Approach 1:

The patent changes the curing temperature parameter from conventional high temperature (180°C) to lower temperature (100-150°C). This parameter change is made possible by optimizing the adhesive composition with specific resin systems and filler content, allowing sufficient void discharge and curing at lower temperatures, thus reducing energy consumption and thermal damage risk.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes the porous structure formed during low-temperature curing to facilitate void discharge. The optimized adhesive composition creates a controlled porous state that allows trapped air and volatiles to escape before the adhesive fully cures, ensuring reliable bonding even at reduced curing temperatures.

Inventive Principle:
Principle #31Porous materials

3Length of stationary object

If film thickness is reduced, then packaging density is improved, but adhesion strength and heat dissipation capability decrease

Engineering Contradiction:
Improveadhesive film thicknessVSAvoidadhesion strength
Core Design Contradiction:
Length of stationary objectVSStrength

Solution Approach 1:

The patent optimizes the adhesive film thickness parameter to a specific range (1-10 μm). This parameter optimization maintains packaging density while ensuring adequate adhesion strength and heat dissipation. The thin film achieves sufficient bonding through optimized composition rather than relying on thickness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite adhesive formulation with epoxy resin, polymer component, and thermally conductive filler that enables thin film construction. The synergistic combination of these materials provides both strong adhesion and effective thermal conduction even at 1-10 μm thickness, eliminating the need for thicker films.

Inventive Principle:
Principle #40Composite materials

4Temperature

If inorganic filler content is increased, then thermal conductivity is improved, but viscosity increases and fluidity decreases

Engineering Contradiction:
Improvethermal conductivityVSAvoidadhesive fluidity
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

The patent changes the filler particle size parameter to large particle diameter (d50: 3.0-10.0 μm), which reduces the number of particles needed for a given volume fraction. This parameter change allows higher filler content (40-70 wt%) without excessive viscosity increase, maintaining both thermal conductivity and fluidity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies surface treatment to the inorganic filler particles to modify their local surface properties. This surface treatment reduces inter-particle friction and improves dispersion, allowing high filler loading while maintaining adequate fluidity for bonding operations.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive enables sufficient curing and void discharge at lower temperatures, improving the thermal conductivity and reliability of semiconductor packages by controlling capillary rheometer viscosity and differential scanning calorimetry measurements.

Implementation Method 1

sufficient curing and void discharge at lower temperatures

Methodology Applied
Scientific EffectCuring reaction: Chemical Bonding

Implementation Method 2

enhanced thermal conductivity

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS20240128154A1Thermally conductive film-like adhesive, semiconductor package, and method of producing same
Publication Date: 2024.04.18 FURUKAWA ELECTRIC CO LTD
  • US20240128154A1 patent drawing
  • US20240128154A1 patent drawing
  • US20240128154A1 patent drawing

AI summary

Provided is a thermally conductive film-like adhesive capable of sufficiently advancing a curing reaction under milder conditions, capable of effectively suppressing residual voids between the adhesive and a wiring board in a semiconductor package to be obtained when used as a die attach film, and capable of obtaining a semiconductor package excellent in heat releasing property inside the package. In addition, provided are a semiconductor package using the thermally conductive film-like adhesive and a method of producing the same.