Die-Casting Die Coating for Semi-Solid Iron Alloy Durability

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Solution Overview

Problem

Current die-casting techniques for semi-liquid or semi-solid iron-based alloys face challenges such as wear, seizure, and corrosion due to high temperatures, leading to a short lifespan of die-casting dies, which limits their durability and productivity.

Innovation Solution

A method involving the application of a lubricating die-release agent with particles like molybdenum disulfide, graphite, tungsten disulfide, boron nitride, or chrome oxide dispersed in a solvent on the inner surfaces of the die's injection port and gate, along with a surface film formed by metal spraying or deposition, enhances the die's durability and releasability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional die-casting dies are used for semi-liquid cast iron, then the die structure is simple, but the durability is poor due to wear, seizure, and thermal shock at high temperatures

Engineering Contradiction:
Improvedie durabilityVSAvoiddie structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The die structure combines multiple materials with different properties: the base member is made of die steel (SKD61) for structural strength, while the inner surface is covered with a nickel-based alloy plating layer for thermal resistance and wear protection. This composite structure allows each material to contribute its optimal properties, significantly improving die durability under high-temperature casting conditions

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The nickel-based alloy plating layer is applied in advance to the die inner surface before casting operations begin. This preliminary protective coating prevents direct contact between the molten cast iron and the die steel, thereby preventing seizure, reducing wear, and protecting against thermal shock before any damage can occur

Inventive Principle:
Principle #10Preliminary action

2Duration of action of moving object

If the die inner surface is directly exposed to semi-liquid cast iron, then the die structure is simple, but wear and seizure occur rapidly reducing lifespan to about a thousand products

Engineering Contradiction:
Improvedie lifespanVSAvoiddie structure complexity
Core Design Contradiction:
Duration of action of moving objectVSDevice complexity

Solution Approach 1:

The die structure combines multiple materials with different properties: the base member is made of die steel (SKD61) for structural strength, while the inner surface is covered with a nickel-based alloy plating layer for thermal resistance and wear protection. This composite structure allows each material to contribute its optimal properties, significantly improving die durability under high-temperature casting conditions

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

A thin plating layer of nickel-based alloy is deposited on the die inner surface, forming a protective film that acts as a barrier between the molten cast iron and the die substrate. This thin film provides sufficient protection against wear and thermal shock while maintaining the structural integrity of the die

Inventive Principle:
Principle #30Flexible shells and thin films

3Reliability

If conventional coatings are applied to improve die durability, then wear resistance improves, but releasability of cast products remains insufficient

Engineering Contradiction:
Improvewear resistanceVSAvoidreleasability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The plating layer uses a nickel-based alloy with specific compositional parameters (containing elements such as Cr, Mo, B) that provide both wear resistance and appropriate surface characteristics for releasability. The controlled composition and microstructure of the plating enable the cast products to be released easily while maintaining protection against wear

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly extends the lifespan of die-casting dies to produce ten to twenty thousand cast products without modification, reduces maintenance time, and improves the quality and accuracy of iron-based alloy castings by preventing wear and seizure.

Implementation Method 1

a lubricating die-release agent in which particles including at least one selected from molybdenum disulfide, graphite, tungsten disulfide, boron nitride, chrome oxide and boric oxide are dispersed in a solvent

Methodology Applied
Scientific EffectSolid lubrication: Lubrication

Implementation Method 2

a lubricating die-release agent in which particles including at least one selected from molybdenum disulfide, graphite, tungsten disulfide, boron nitride, chrome oxide and boric oxide are dispersed in a solvent

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP2301689B1Method of casting semi-liquid or semi-solid iron-based alloy and die for casting
Publication Date: 2019.11.06 NIPPON STEEL CORPORATION
  • EP2301689B1 patent drawingFigure 1
  • EP2301689B1 patent drawingFigure 2~3
  • EP2301689B1 patent drawingFigure 4~5

AI summary

A method of casting a semi-liquid or semi-solid iron-based alloy, the method including: applying, to a part or to the whole of an uppermost surface of an inner surface of a die, a lubricating die-release agent in which particles including at least one selected from molybdenum disulfide, graphite, tungsten disulfide, boron nitride, chrome oxide and boric oxide are dispersed in a solvent; and thereafter casting by using the die.