Dielectric Back Reflector for Solar Cell Light Management
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Solution Overview
Problem
Solar cells face challenges with expensive metal back reflector/electrode structures and texturing processes that increase costs and can degrade performance, particularly due to plasmonic losses and chemical reactivity, necessitating a cost-effective and performance-optimizing solution.
Innovation Solution
A photovoltaic device with a periodic array of dome or dome-like protrusions at the front surface and a metal-less back reflector/electrode structure that refracts light and provides optical impedance matching, eliminating the need for expensive metals and texturing, using transparent conductive materials and avoiding plasmonic losses.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If metal back reflector/electrode structures are used, then optical reflectivity and electrical conductivity are improved, but device cost and manufacturing complexity increase
Solution Approach 1:
The patent replaces expensive metal back reflectors with inexpensive dielectric materials such as silicon nitride, silicon oxide, or titanium dioxide. These materials can be deposited using standard semiconductor processing techniques like plasma-enhanced chemical vapor deposition (PECVD) or atomic layer deposition (ALD), eliminating the need for costly vacuum deposition processes required for metals like silver or aluminum.
Solution Approach 2:
The invention employs composite dielectric structures with multiple layers of different materials (e.g., alternating layers of silicon nitride and silicon oxide) to achieve superior optical reflectivity through constructive interference of reflected light waves. This composite approach allows tuning of the reflector's optical properties by adjusting layer thicknesses and material compositions to match specific wavelength ranges.
2Reliability
If metal back reflector/electrode structures are used, then optical reflectivity is improved, but plasmonic losses and chemical reactivity increase
Solution Approach 1:
The patent replaces expensive metal back reflectors with inexpensive dielectric materials such as silicon nitride, silicon oxide, or titanium dioxide. These materials can be deposited using standard semiconductor processing techniques like plasma-enhanced chemical vapor deposition (PECVD) or atomic layer deposition (ALD), eliminating the need for costly vacuum deposition processes required for metals like silver or aluminum.
Solution Approach 2:
The invention converts the typically harmful plasmonic losses in metals into beneficial optical field enhancement at dielectric interfaces. By strategically designing the refractive index contrast and layer thicknesses of the dielectric stack, the patent creates regions of enhanced optical field intensity that increase light absorption in the active layer, thereby transforming what would be energy loss into useful photoelectric conversion.
3Reliability
If texturing processes are used, then light management is improved, but manufacturing complexity and cost increase
Solution Approach 1:
The patent replaces mechanical texturing processes (such as chemical etching or physical surface modification) with an optical approach using dielectric mirror stacks. By controlling the thickness and refractive index of deposited dielectric layers, the system achieves light management functions through optical interference effects rather than physical surface modification, eliminating complex wet chemistry or plasma etching steps.
Solution Approach 2:
The invention achieves light management by precisely controlling parameters of the dielectric layers, specifically thickness and refractive index. By adjusting these parameters during deposition, the system optimizes optical reflectivity and light absorption without requiring any surface texturing. This parameter-based control is achieved through standard thin-film deposition techniques with precise thickness monitoring.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution enhances photon momentum parallel to the back contact, improving short circuit current and reducing manufacturing costs by eliminating the need for expensive metals and complex texturing processes, while maintaining superior performance comparable to metal-based structures.
Implementation Method 1
refract the incoming light in a manner to thereby provide photons with an advantageous larger momentum component parallel to the plane of the back (R/EBC) contact
Implementation Method 2
provide optical impedance matching for the short wavelength incoming light
Implementation Method 3
Each reflector/back electrode form operates as a back light reflector
Data Source
AI summary
A photovoltaic or light detecting device is provided that includes a periodic array of dome or dome-like protrusions at the light impingement surface and three forms of reflector/back electrode at the device back. The beneficial interaction between an appropriately designed top protrusion array and these reflector/electrode back contacts (R/EBCs) serve (1) to refract the incoming light thereby providing photons with an advantageous larger momentum component parallel to the plane of the back (R/EBC) contact and (2) to provide optical impedance matching for the short wavelength incoming light. The reflector/back electrode operates as a back light reflector and counter electrode to the periodic array of dome or dome-like structures. A substrate supports the reflector/back electrode.


