Dielectric Composite Grain Boundary Insulation Layer

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Solution Overview

Problem

Conventional multi-layer ceramic capacitors face challenges in achieving smaller size, greater thinness, and higher capacity while maintaining high relative permittivity, as the thickness of the grain boundary insulation layer decreases, leading to reduced capacitance.

Innovation Solution

Incorporating a two-dimensional layered material with high relative permittivity, such as delaminated metal oxide nano sheets from aurivillius or Ruddlesden-Popper phases, into the grain boundary insulation layer, allowing for ultra-thin films with maintained or enhanced capacitance properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If the thickness of the grain boundary insulation layer is decreased to achieve smaller size and greater thinness, then the capacitor capacity is improved, but the relative permittivity is reduced

Engineering Contradiction:
Improvecapacitor sizeVSAvoidrelative permittivity
Core Design Contradiction:
Volume of moving objectVSReliability

Solution Approach 1:

The patent applies composite materials by combining two-dimensional layered materials (such as transition metal dichalcogenides, hexagonal boron nitride, or graphitic carbon nitride) with conventional dielectric materials in the grain boundary insulation layer. This composite structure enables the maintenance of high relative permittivity even when the overall layer thickness is reduced to several to several tens of nanometers, thereby resolving the contradiction between miniaturization and permittivity preservation

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the material parameters by introducing two-dimensional layered materials with inherently high relative permittivity values into the grain boundary insulation layer. This parameter change allows the layer to achieve both ultra-thin dimensions (several to tens of nanometers) and high relative permittivity simultaneously, overcoming the conventional trade-off where thinner layers exhibit reduced permittivity

Inventive Principle:
Principle #35Parameter changes

2Length of stationary object

If the thickness of the grain boundary insulation layer is decreased to achieve greater thinness, then the capacitor can be made thinner, but the capacitance is reduced

Engineering Contradiction:
Improvefilm thicknessVSAvoidcapacitance
Core Design Contradiction:
Length of stationary objectVSReliability

Solution Approach 1:

By incorporating two-dimensional layered materials with high relative permittivity into the grain boundary insulation layer, the composite structure compensates for the reduced thickness. The high permittivity of the two-dimensional material maintains the capacitance value even when the film thickness is reduced to several to several tens of nanometers, enabling ultra-thin capacitors with preserved capacitance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The introduction of two-dimensional layered materials fundamentally changes the dielectric parameters of the grain boundary insulation layer. This material substitution enables the layer to achieve both ultra-thin dimensions (several to tens of nanometers) and high capacitance simultaneously, breaking the conventional inverse relationship between thickness and capacitance

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The dielectric composite achieves high relative permittivity even at nanometer thicknesses, enabling the creation of smaller, thinner capacitors with improved capacitance, overcoming limitations of conventional intergranular insulation type capacitors.

Implementation Method 1

The two-dimensional layered material may have a relative permittivity of greater than or equal to about 50 and less than or equal to about 1000

Methodology Applied
Scientific EffectDielectric permittivity: Dielectric Permittivity

Data Source

PatentEP3351521B1Dielectric composites, and multi-layered capacitors and electronic devices comprising thereof
Publication Date: 2021.10.06 SAMSUNG ELECTRONICS CO LTD
  • EP3351521B1 patent drawingFigure 1
  • EP3351521B1 patent drawingFigure 2
  • EP3351521B1 patent drawingFigure 3

AI summary

A dielectric composite including a plurality of crystal grains including a semiconductor or conductive material, and a grain boundary insulation layer between the crystal grains, wherein the grain boundary insulation layer includes a two-dimensional layered material covering at least a portion of a surface of at least one of the crystal grains, and a multi-layered capacitor and an electronic device including the same.