Dielectric Layer Thermal Treatment for EUV Shrinkage

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Solution Overview

Problem

As semiconductor devices continue to shrink, extreme ultraviolet lithography (EUVL) causes material property changes and thickness shrinkage in dielectric layers, leading to challenges in maintaining pattern fidelity and film quality due to the high energy deposition of EUV radiation.

Innovation Solution

Thermal treatment processes are applied to dielectric layers before EUVL processing, which include heating to temperatures up to 400°C and exposure to ultraviolet radiation, to densify the material structure and reduce EUV-induced changes, thereby stabilizing the film and reducing thickness shrinkage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If EUVL is used for manufacturing smaller semiconductor devices, then manufacturing precision is improved, but material property changes and thickness shrinkage occur in dielectric layers

Engineering Contradiction:
Improvedevice dimension precisionVSAvoiddielectric layer material stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent applies thermal treatment to dielectric layers before EUVL processing to densify the material structure in advance. This preliminary densification reduces the dielectric layer's sensitivity to EUV radiation, preventing thickness shrinkage and material property changes during subsequent lithography operations.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the physical state and structural parameters of the dielectric layer through thermal treatment. By heating the dielectric layer to specific temperatures (e.g., 400-800°C), the material undergoes structural transformation that increases its density and stability, making it resistant to EUV-induced changes.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If thermal treatment is applied to densify dielectric layers, then EUV-induced material property changes are reduced, but processing complexity increases

Engineering Contradiction:
Improvedielectric layer stabilityVSAvoidprocessing steps
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent combines the thermal treatment step with existing semiconductor manufacturing process flows. The thermal annealing is integrated into the sequence of deposition, lithography, and etching operations, allowing the densification process to be performed using standard equipment and process integration techniques.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The thermal treatment effectively reduces EUV-induced material property changes and thickness shrinkage, improving the heat and radiation resistance of dielectric layers, and enhancing the bulk film quality, allowing for more precise and reliable semiconductor device fabrication.

Implementation Method 1

Thermal treatment processes are applied to dielectric layers before EUVL processing, which include heating to temperatures up to 400°C

Methodology Applied
Scientific EffectThermal treatment: Heating

Implementation Method 2

exposure to ultraviolet radiation, to densify the material structure and reduce EUV-induced changes

Methodology Applied
Scientific EffectUltraviolet radiation exposure: Photo-oxidation

Data Source

PatentUS10510538B2Reducing EUV-induced material property changes
Publication Date: 2019.12.17 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US10510538B2 patent drawing
  • US10510538B2 patent drawing
  • US10510538B2 patent drawing

AI summary

Representative systems and methods for preventing or otherwise reducing extreme-ultraviolet-induced material property changes (e.g., layer thickness shrinkage) include one or more thermal treatments to at least partially stabilize a material forming a material layer disposed over a substrate prior to extreme ultraviolet (EUV) exposure (e.g., wavelengths spanning about 124 nm to about 10 nm) attendant to photolithographic processing. Representative systems and methods provide for reduction of average compressive stress in a material layer after thermal treatment prior to extreme EUV photolithographic patterning. Representative thermal treatments may include one or more annealing processes, ultraviolet (UV) radiation treatments, ion implantations, ion bombardments, plasma treatments, surface baking treatments, surface coating treatments, surface ashing treatments, or pulsed laser treatments.