Dielectric Seasoning Films for High-Voltage Electrostatic Chucks

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Solution Overview

Problem

Conventional electrostatic chucks experience increased leakage currents at higher chucking voltages due to the electrical conductivity of their seasoning films, limiting the ability to counteract substrate warping from cumulative stress during multilayer deposition.

Innovation Solution

The use of dielectric seasoning films with a dielectric constant greater than 3.5 and reduced leakage currents, applied with voltages up to 500 V, to enhance electrostatic chucking forces and reduce arcing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional seasoning films are used on electrostatic chucks, then the chuck can hold substrate wafers, but leakage current increases at higher chucking voltages

Engineering Contradiction:
Improveelectrostatic chucking forceVSAvoidleakage current
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent changes the dielectric constant parameter of the seasoning film from conventional values (typically κ < 3.5) to higher values (κ > 3.5). This parameter change increases the electrical insulation performance of the seasoning film, thereby reducing leakage current while maintaining electrostatic chucking force. The higher dielectric constant allows the film to better insulate the high voltage applied to the electrostatic chuck, preventing charge leakage through the film.

Inventive Principle:
Principle #35Parameter changes

2Force

If higher chucking voltages are applied to counteract substrate warping, then electrostatic chucking force increases, but leakage current increases

Engineering Contradiction:
Improveelectrostatic chucking forceVSAvoidleakage current
Core Design Contradiction:
ForceVSLoss of energy

Solution Approach 1:

The patent introduces an improved seasoning film as an intermediary layer between the electrostatic chuck surface and the substrate wafer. This intermediary layer with high dielectric constant (κ > 3.5) acts as a better electrical insulator, allowing higher chucking voltages to be applied without proportionally increasing leakage current. The film mediates between the high voltage requirement for counteracting substrate warping and the need to minimize energy loss through leakage.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Adaptability or versatility

If multilayer deposition is performed to create integrated circuits, then device complexity and functionality increase, but cumulative stress causes substrate warping

Engineering Contradiction:
Improvedevice functionalityVSAvoidsubstrate warping
Core Design Contradiction:
Adaptability or versatilityVSShape

Solution Approach 1:

The patent applies preliminary anti-action by using the electrostatic chuck with high dielectric constant seasoning film to counteract the warping force before it significantly affects substrate processing. The high chucking voltage (enabled by the low leakage current film) generates strong electrostatic forces that hold the substrate flat against the chuck surface, preemptively preventing warping from compromising the multilayer deposition process. This preliminary counter-action maintains substrate planarity throughout the fabrication process.

Inventive Principle:
Principle #9Preliminary anti-action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach maintains high electrostatic chucking forces while minimizing leakage currents, allowing for increased voltage application and reduced substrate warping, even at elevated temperatures.

Implementation Method 1

The seasoning films may include dielectric materials characterized by dielectric constants (κ-values) of greater than or about 3.5

Methodology Applied
Scientific EffectDielectric polarization: Dielectric

Implementation Method 2

systems and methods of seasoning electrostatic chucks with dielectric seasoning films that permit the chuck to hold a high amount of static charge

Methodology Applied
Scientific EffectElectrostatic force: Electrostatics

Data Source

PatentUS12381106B2Systems and methods of seasoning electrostatic chucks with dielectric seasoning films
Publication Date: 2025.08.05 APPLIED MATERIALS INC
  • US12381106B2 patent drawing
  • US12381106B2 patent drawing
  • US12381106B2 patent drawing

AI summary

Semiconductor processing systems and method are described that may include flowing deposition precursors into a substrate processing region of a semiconductor processing chamber, where the substrate processing region includes an electrostatic chuck. The methods may further include depositing a seasoning layer on the electrostatic chuck from the deposition precursors to form a seasoned electrostatic chuck. The seasoning layer may be characterized by a dielectric constant greater than or about 3.5. The methods may still further include applying a voltage to the seasoned electrostatic chuck of greater than or about 500 V. The seasoned electrostatic chuck may be characterized by a leakage current of less than or about 25 mA when the voltage is applied.