Highly Saturated Diene Rubber Composition for Tire Tread Grip
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Solution Overview
Problem
Tire manufacturers seek rubber compounds for highly saturated diene elastomer treads that improve rolling resistance without compromising wet grip performance.
Innovation Solution
A rubber composition combining a highly saturated diene elastomer with a high Tg resin, comprising a reinforcing filler and a vulcanization system, which balances rolling resistance and wet grip by using a high Tg hydrocarbon resin with specific molecular characteristics.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If SBR-type diene elastomer is used in tire tread, then wet grip performance is improved, but rolling resistance increases
Solution Approach 1:
The patent changes the chemical composition parameters by using highly saturated diene elastomer (≥85% saturation) combined with specific resin ratios (aromatic resin 10-40 parts, aliphatic resin 10-40 parts per 100 parts elastomer). This parameter optimization achieves both low rolling resistance (tan δ at 23°C ≤0.085) and good wet grip (tan δ integral from -40°C to 0°C ≥0.45), resolving the contradiction between energy loss and reliability.
2Loss of energy
If highly saturated diene elastomer is used to reduce rolling resistance, then energy loss is reduced, but wet grip performance deteriorates
Solution Approach 1:
The patent creates a composite rubber composition by combining highly saturated diene elastomer with a specific blend of aromatic and aliphatic resins. The aromatic resin provides structural integrity and low-temperature flexibility, while the aliphatic resin enhances adhesion and wet grip. This composite approach maintains low rolling resistance (≤0.085 tan δ at 23°C) while achieving good wet grip (≥0.45 tan δ integral), thus resolving the contradiction between energy efficiency and reliability.
3Loss of energy
If high Tg resin is added to improve rolling resistance, then energy loss is reduced, but compound complexity increases
Solution Approach 1:
The patent optimizes the resin content parameters within specific ranges (aromatic resin 10-40 parts, aliphatic resin 10-40 parts per 100 parts elastomer) to achieve the desired balance between rolling resistance and compound simplicity. By controlling these parameters, the formulation achieves low rolling resistance (tan δ at 23°C ≤0.085) without excessive complexity, and maintains good processability and vulcanization characteristics.
Data Source
AI summary
The present invention relates to a rubber composition based on at least one elastomer matrix comprising mainly a highly saturated diene elastomer, a reinforcing filler, a vulcanisation system and a plasticising system including a hydrocarbon resin having a Tg of between 50°C and 120°C and an aliphatic proton level of greater than or equal to 95%, and a number-average molar mass (Mn) of less than or equal to 800 g/mol; the highly saturated diene elastomer being a copolymer of ethylene and at least one 1,3-diene of formula (I), CH2=CR-CH=CH2 (I), R representing a hydrocarbon chain having between 3 and 20 carbon atoms, in which the ethylene units represent at least 50 mol% of the monomer units of the copolymer.