Diffuse-Light Absorption Spectroscopy for Mycotoxin Detection in Cereals

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Solution Overview

Problem

Current methods for detecting deoxynivalenol (DON) in cereals are time-consuming, expensive, and destructive, and fail to provide a non-destructive, localized contamination assessment, especially for individual cereal kernels, which is crucial for ensuring food safety and compliance with regulatory limits.

Innovation Solution

A method using diffuse-light absorption spectroscopy with integrating spheres to capture and analyze the absorption spectra of cereal grains, employing multivariate data analysis and chemometric techniques to classify contamination levels, enabling non-destructive, fast, and accurate detection of mycotoxins like DON in individual cereal kernels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If chemical analysis methods (LC-MS/MS, ELISA) are used to detect DON, then measurement precision is improved, but productivity deteriorates due to time-consuming procedures

Engineering Contradiction:
Improvedetection accuracyVSAvoiddetection speed
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The patent replaces complex mechanical/chemical analysis systems (LC-MS/MS, ELISA) with an optical detection system based on near-infrared spectroscopy. This substitution maintains sufficient detection precision while dramatically improving productivity by enabling rapid, non-destructive screening of individual kernels without time-consuming sample preparation and analysis procedures.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent creates an optical copy (spectral signature) of the mycotoxin contamination in cereal kernels. By capturing near-infrared absorption spectra and analyzing them through multivariate data analysis, the system generates a digital representation of contamination levels that correlates with chemical analysis results, enabling fast detection without physical destruction of samples.

Inventive Principle:
Principle #26Copying

2Measurement precision

If sample-based chemical analysis is used, then measurement precision is improved, but loss of information deteriorates due to destructive sampling

Engineering Contradiction:
Improvecontamination level detectionVSAvoidsample integrity
Core Design Contradiction:
Measurement precisionVSLoss of information

Solution Approach 1:

The patent enables the sample (cereal kernel) to serve itself in the detection process. The near-infrared spectroscopy method is non-destructive, allowing the kernel to remain intact after measurement. This self-service approach preserves sample integrity, enabling subsequent testing, retesting, or other uses of the same sample while still providing accurate contamination level information.

Inventive Principle:
Principle #25Self-service

3Productivity

If spectroscopic detection is applied to individual kernels, then productivity is improved through rapid screening, but measurement precision deteriorates due to localized contamination variability

Engineering Contradiction:
Improvescreening throughputVSAvoidcontamination classification accuracy
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent segments the detection process into two distinct stages: (1) rapid screening of individual kernels using near-infrared spectroscopy to identify potentially contaminated kernels, and (2) detailed analysis of collected spectra using multivariate data analysis methods. This segmentation allows high-speed initial screening while maintaining precision through sophisticated spectral interpretation algorithms that account for localized contamination variability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent transforms the raw spectral data into meaningful contamination information through parameter changes in the data analysis process. By applying multivariate data analysis techniques to the near-infrared spectra, the system converts complex spectral variations into clear contamination level classifications, maintaining measurement precision even when detecting localized contamination in individual kernels.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the rapid, accurate, and non-destructive detection of mycotoxins in cereals, suitable for industrial implementation, enhancing food safety and reducing economic losses by monitoring individual kernel contamination levels without damaging the grains.

Implementation Method 1

capturing at least one diffuse-light absorption spectrum of a collection of unprocessed cereal grains using an integrating sphere

Methodology Applied
Scientific EffectDiffuse-light absorption spectroscopy: Absorption Spectroscopy

Implementation Method 2

capturing at least one diffuse-light absorption spectrum using an integrating sphere

Methodology Applied
Scientific EffectLight scattering: Scattering

Data Source

PatentEP3211400B1A method and apparatus for the detection of the presence of mycotoxins in cereals
Publication Date: 2020.07.22 TOMRA SORTING NV
  • EP3211400B1 patent drawingFigure 1
  • EP3211400B1 patent drawingFigure 2
  • EP3211400B1 patent drawingFigure 3a~3b

AI summary

A method and apparatus for detecting the presence of mycotoxins in cereals, the method comprising: capturing at least one diffuse-light absorption spectrum of a collection of cereal grains; capturing at least one diffuse-light absorption spectrum of at least one individual cereal grain from the collection of cereal grains; and classifying the level of mycotoxin contamination in at least one cereal grain by performing multivariate data analysis on the at least one diffuse-light absorption spectrum of the collection of cereal grains and the at least one diffuse-light absorption spectrum of the at least one individual cereal grain.