Low Refractive Index Diffuser With Interconnected Voids

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Solution Overview

Problem

Existing methods for creating porous or voided articles are limited by the need for washing steps to remove surfactants and chemical residues, which restricts pore size and uniformity, and are limited in the types of materials that can be used.

Innovation Solution

A low refractive index diffuser layer is developed, comprising a binder, metal oxide particles, interconnected voids, and haze generating particles, with an effective refractive index of 1.3 or less, which reduces the need for multiple optical elements in display applications by incorporating a composite structure of fumed metal oxides and polymeric binders.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional porous article creation methods (PIPS, TIPS, SIPS, emulsion polymerization, polymerization with foaming agents) are used, then porous structures can be formed, but washing steps are required to remove surfactants and chemical residues, which limits pore size ranges and uniformity

Engineering Contradiction:
Improvepore size uniformityVSAvoidmanufacturing process complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention extracts and eliminates the washing step from the manufacturing process by using a polymerization method that does not require surfactants or chemical residues. The porogen particles are removed through extraction with a solvent, leaving clean pores without requiring additional washing steps to remove chemical residues.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention uses porous polymer beads as porogens that can be easily extracted after polymerization. These porous beads provide a template for forming uniform pores in the final product, and their porous structure allows for complete removal via solvent extraction, achieving uniform pore sizes without residual chemicals.

Inventive Principle:
Principle #31Porous materials

2Adaptability or versatility

If conventional porous article creation methods are used, then porous structures can be formed, but the types of materials that can be used are limited

Engineering Contradiction:
Improvematerial selection rangeVSAvoidmanufacturing process constraints
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The invention uses a universal polymerization approach that can accommodate various monomers and porogen materials. The free radical polymerization method works with different vinyl monomers, and the porogen can be any material that can be extracted with a solvent, greatly expanding material selection flexibility.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The invention creates composite structures during polymerization where the polymer matrix and porogen particles coexist. This composite approach allows combining different materials with complementary properties, such as using inorganic porogens in organic polymer matrices, expanding the range of usable materials.

Inventive Principle:
Principle #40Composite materials

3Reliability

If multiple optical elements are used in display applications, then optical performance can be achieved, but the number of components and assembly complexity increases

Engineering Contradiction:
Improveoptical performanceVSAvoidnumber of optical elements
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention combines multiple optical functions (diffusion, refractive index control, and structural integrity) into a single porous polymer article. This eliminates the need for separate optical elements, reducing assembly complexity while maintaining optical performance through the integrated porous structure.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention controls optical properties by adjusting parameters of the porous structure, such as pore size, porosity, and distribution. By varying these parameters during polymerization and extraction, different optical performances can be achieved within a single element, replacing multiple elements with different fixed properties.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a low refractive index and high optical haze, reducing the number of optical elements required in display applications while maintaining durability and processing quality.

Implementation Method 1

a binder, a plurality of metal oxide particles dispersed in the binder

Methodology Applied
Scientific EffectComposite materials: Composite Materials

Implementation Method 2

a plurality of interconnected voids... The optical diffuser layer has an effective refractive index of 1.3 or less

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 3

a plurality of interconnected voids

Methodology Applied
Scientific EffectPorosity: Porosity

Implementation Method 4

A plurality of haze generating particles are dispersed in the binder

Methodology Applied
Scientific EffectLight scattering: Scattering

Data Source

PatentUS9465145B2Low refractive index diffuser element having interconnected voids
Publication Date: 2016.10.11 3M INNOVATIVE PROPERTIES CO
  • US9465145B2 patent drawing
  • US9465145B2 patent drawing
  • US9465145B2 patent drawing

AI summary

An optical diffuser layer includes a binder, a plurality of metal oxide particles dispersed in the binder, and a plurality of interconnected voids. A plurality of haze generating particles are dispersed in the binder. The optical diffuser layer has an effective refractive index of 1.3 or less.