Diffusion Bonding of Oxide-Forming Metals Using Evaporative Coatings

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Solution Overview

Problem

Conventional diffusion bonding techniques face challenges in bonding metal or metal alloy workpieces with tenacious surface oxide layers, such as aluminium, due to issues like harsh cleaning processes, environmental hazards, grain coarsening, and less-than-optimum bond strengths, especially for precision components.

Innovation Solution

A method involving coating the bonding surfaces with a liquid coating material that forms a stable barrier, abrades the oxide layer, removes excess material, and then diffuses the workpieces under controlled conditions, using environmentally-safe chemicals and avoiding extreme roughening or polymer coatings.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cleaning processes are used to remove surface oxide layers, then bonding surfaces are cleaned, but harsh chemicals and environmental hazards are introduced

Engineering Contradiction:
Improvebonding qualityVSAvoidenvironmental harm
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

A coating material is applied as an intermediary layer on the bonding surface before abrasion. This coating material facilitates the removal of surface oxide layers through mechanical abrasion without requiring harsh chemical cleaners, thereby eliminating environmental hazards while maintaining bonding quality

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention replaces chemical cleaning methods with a mechanical abrasion process. By applying a coating material that can be mechanically abraded to remove oxide layers, the process eliminates the need for harsh chemical cleaners and environmentally harmful substances

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If grit blasting is used to remove oxide layers, then cleaning is effective, but grain coarsening occurs at the bonding interface

Engineering Contradiction:
Improveoxide removal effectivenessVSAvoidsurface grain structure
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The invention changes the parameters of the abrasion process by using a coating material with specific mechanical properties that can be abraded controllably. This allows effective oxide removal while maintaining control over the abrasion intensity, preventing excessive grain coarsening at the bonding interface

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The coating material serves as an intermediary that is abraded during the cleaning process. This intermediary layer protects the underlying metal surface from direct exposure to aggressive blasting media, thereby removing oxide layers while preserving the base metal's grain structure

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If electropolishing is used to prepare surfaces, then bonding quality improves, but the process is undesirable for large scale use due to complexity

Engineering Contradiction:
Improvebonding qualityVSAvoidprocess scalability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention replaces the complex electrochemical electropolishing process with a simpler mechanical abrasion process. By applying a coating material that can be mechanically abraded to achieve the desired surface preparation, the process becomes more scalable and suitable for large-scale production while maintaining bonding quality

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention extracts the essential function of electropolishing (surface preparation for bonding) and achieves it through a different, simpler mechanism. The coating material abrasion process provides the necessary surface preparation without requiring the complex electrochemical equipment and procedures of electropolishing

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Facilitates effective diffusion bonding of metal or metal alloy workpieces with tenacious surface oxide layers, ensuring strong bonds without environmental harm, avoiding harsh cleaning and extreme roughening, and maintaining bond quality for precision components.

Implementation Method 1

the coating material is operable to form a stable barrier on the bonding surfaces of the metal or metal alloy containing workpieces under ambient conditions

Methodology Applied
Scientific EffectBarrier formation:

Implementation Method 2

evaporates from the bonding surfaces of the metal or metal alloy containing workpieces under diffusion bonding conditions

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

It utilises a combination of applied pressure (load) and elevated temperature to accelerate the diffusion of atoms across an interface and bond workpieces together

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentEP3790701B1A method of diffusion bonding
Publication Date: 2024.09.18 TWI LTD
  • EP3790701B1 patent drawingFigure 1

AI summary

The present invention relates to a method of diffusion bonding metal or metal alloy containing workpieces, the method comprising (a) coating the bonding surfaces of the metal or metal alloy containing workpieces with a layer of a coating material, (b) abrading the coated bonding surfaces top remove surface oxide, the coating material being in a liquid form, (c) removing excess coating material or excess abraded metal or metal alloy containing workpiece material from the coated bonding surfaces, and (d) diffusion bonding the coated bonding surfaces of the metal or metal alloy containing workpieces together, wherein the coating material is operable to form a stable barrier on the bonding surfaces of the metal or metal alloy containing workpieces under ambient conditions, and evaporates from the bonding surfaces of the metal or metal alloy containing workpieces under diffusion bonding conditions. The invention also relates to a bonded workpiece formed using the method of diffusion bonding metal or metal alloy containing workpieces.