Diffusive Sampling Device with Interchangeable Porous Membranes

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Solution Overview

Problem

Existing diffusive sampling devices are limited by design for specific applications, leading to issues such as low or high sampling rates, saturation, contamination, and difficulty in handling and transporting samples, which affects their operational performance and versatility.

Innovation Solution

A compact, versatile diffusive sampling device with a porous hollow diffusion body and adsorbent body, featuring a cylindrical shape with radial and axial adsorption capabilities, allowing for easy assembly, manipulation, and interchangeability of diffusion bodies with varying porosities and materials, along with a removable design for cleaning and compatibility with conventional desorption equipment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If diffusive samplers are designed for specific applications with fixed sampling rates, then sampling performance is optimized for particular conditions, but versatility and adaptability to different sampling conditions are reduced

Engineering Contradiction:
Improvesampling performanceVSAvoidadaptability to different sampling conditions
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The sampler design incorporates interchangeable diffusion membranes with different porosity values (e.g., 10%, 20%, 30%, 40%) that can be selected based on the specific analyte and sampling conditions. The support body and housing structure remain universal, allowing the same base design to function across multiple applications by simply changing the membrane component.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The diffusion membrane is designed as a separate, removable component that can be independently replaced. This segmentation allows users to swap membranes without replacing the entire sampler, enabling adaptation to different sampling requirements while maintaining the core device structure.

Inventive Principle:
Principle #1Segmentation

2Reliability

If diffusion path length is increased to reduce sampling rate and prevent saturation, then adsorbent saturation is reduced, but device length and complexity increase

Engineering Contradiction:
Improveprevention of adsorbent saturationVSAvoiddevice length
Core Design Contradiction:
ReliabilityVSLength of stationary object

Solution Approach 1:

Instead of uniformly increasing the diffusion path length throughout the entire device, the invention modifies the local property of the diffusion membrane by adjusting its porosity. This allows control of the sampling rate through membrane selection rather than through device geometry changes, maintaining a compact form factor.

Inventive Principle:
Principle #3Local quality

3Measurement precision

If sampling rate is increased to achieve higher sensitivity and shorter sampling times, then detection sensitivity improves, but adsorbent saturation occurs more quickly

Engineering Contradiction:
Improvedetection sensitivityVSAvoidsampling duration before saturation
Core Design Contradiction:
Measurement precisionVSDuration of action of stationary object

Solution Approach 1:

The system provides dynamic adjustability of the sampling rate by allowing users to select different diffusion membranes based on the expected analyte concentration and desired sampling duration. High porosity membranes (e.g., 40%) are used for low concentrations requiring high sensitivity, while low porosity membranes (e.g., 10%) are used for high concentrations requiring longer sampling periods.

Inventive Principle:
Principle #15Dynamics

4Ease of manufacture

If diffusion membranes are made reusable and exposed to ambient conditions, then cost is reduced, but membranes deteriorate over time and become contaminated with graphitized adsorbent

Engineering Contradiction:
Improvecost reductionVSAvoidmembrane performance stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The diffusion membranes are designed as disposable components that can be easily replaced. After use, membranes are discarded rather than cleaned and reused, eliminating contamination issues while keeping the overall system cost-effective due to the simple, reusable support body and housing structure.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device provides enhanced sensitivity, ease of use, and adaptability for various sampling conditions, reducing manufacturing costs and blank levels, while maintaining high sensitivity and reproducibility, and is suitable for both stationary and mobile applications.

Implementation Method 1

Passive diffusive sampling relies on the diffusion of analytes through a diffusive surface onto an adsorbent

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

the analyte be collected owing to the concentration gradient between the bulk ambient air concentration and a retention medium (i.e. solid adsorbent, liquid or gel absorbent)

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS10024769B2Diffusive sampling device
Publication Date: 2018.07.17 EUROPEAN COMMUNITY (EC)
  • US10024769B2 patent drawing
  • US10024769B2 patent drawing
  • US10024769B2 patent drawing

AI summary

A diffusive sampling device (1) comprises a porous hollow diffusion body (3) removably held on a support body (2), an adsorbent body (4) located inside said diffusion body (3), wherein the hollow diffusion body (3) has a cylindrically shaped wall with an upper section comprising a closed upper end and a distal lower section comprising an open lower end and wherein the diffusion body (3) is held on the support body (2) by means of one or more o-rings (7) fixed to its lower section, wherein the adsorbent body (4) is kept in a predetermined place inside the upper section of the diffusion body (3) by way of an elastic means, such as a spring (6). The use of such devices as well as a method for air sampling and monitoring.