2,3-Difluorophenyl Liquid Crystal Compounds for VA-Mode Displays

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Solution Overview

Problem

Current liquid crystal compounds for VA-mode displays face limitations in achieving optimal performance metrics such as clearing point and negative dielectric constant, which affect display quality and efficiency.

Innovation Solution

Development of a negative dielectric anisotropic liquid crystal compound containing 2,3-difluorophenyl with specific structural formulas and preparation methods, allowing for the formulation of liquid crystal mixtures that enhance the clearing point and negative dielectric constant.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional liquid crystal compounds are used for VA-mode displays, then the display can achieve basic functionality, but the clearing point and negative dielectric constant are insufficient, limiting display quality and efficiency

Engineering Contradiction:
Improvedisplay qualityVSAvoidclearing point
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent modifies the molecular structure of liquid crystal compounds by introducing specific chemical groups (2,3-difluorophenyl, cyclobutyl, cyclopentyl) and varying substituent positions and types (R1-R6 groups including alkyl, alkoxy, fluoro, and chloro groups). These structural parameter changes directly influence the clearing point and dielectric constant, enabling optimization of display performance while maintaining thermal stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops liquid crystal mixtures comprising multiple compounds with different molecular structures and properties. By combining compounds containing cyclobutyl, cyclopentyl, and 2,3-difluorophenyl groups with various substituents, the mixture achieves synergistic effects that simultaneously improve clearing point, negative dielectric constant, and overall display quality beyond what single compounds can provide.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional liquid crystal compounds are used for VA-mode displays, then the display can achieve basic functionality, but the negative dielectric constant is insufficient, affecting display efficiency

Engineering Contradiction:
Improvedisplay efficiencyVSAvoidnegative dielectric constant
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent systematically varies molecular parameters including the type of terminal groups (cyclobutyl vs. cyclopentyl), the nature of substituents (R1-R6 groups with different electronic and steric properties), and their positions on the molecular structure. These parameter changes are specifically designed to enhance the negative dielectric constant while maintaining or improving clearing point, thereby optimizing both display efficiency and reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent formulates liquid crystal mixtures that combine multiple compounds with complementary properties. The mixture includes compounds with cyclobutyl and cyclopentyl groups, various aromatic substituents, and different chain lengths, creating a synergistic system where the combined effect produces a higher negative dielectric constant and improved display efficiency than individual components alone.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS9517990B2Negative dielectric anisotropic liquid crystal compounds containing 2,3-difluorophenyl group, and preparation method and use thereof
Publication Date: 2016.12.13 SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIALS CO LTD
  • US9517990B2 patent drawing
  • US9517990B2 patent drawing
  • US9517990B2 patent drawing

AI summary

A negative dielectric anisotropic liquid crystal compound containing 2,3-difluorophenyl, and a preparation method and use thereof are disclosed. The compound has a general structural formula as shown in Formula I. The negative dielectric anisotropic liquid crystal compound has a negative dielectric anisotropy (Δ∈), and has cyclobutyl or cyclopentyl as a terminal group. Compared with conventional liquid crystal compounds with a flexible alkyl chain as a terminal group, the compound of Formula I according to the present invention has the advantage of high clearing point, and enables extension of the application range of a liquid crystal mixture because a positive correlation exists between the clearing points of the liquid crystal mixture and monomer liquid crystal compounds. In addition, the compound can increase the absolute value of the negative dielectric constant of the liquid crystal mixture, thus having an important application value.