Digester Washing Liquid Circulation for Pulp Hydrolysate Recovery

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Solution Overview

Problem

Existing prehydrolysis-sulfate cooking processes for producing high-alpha cellulose pulps face inefficiencies in hydrolysate recovery, leading to uneven treatment, energy inefficiency, and dilute carbohydrate solutions, which affect pulp quality and sulfur contamination.

Innovation Solution

A displacement batch pulping process that introduces hot washing liquid from the bottom of the digester, circulates it through suction screens, and neutralizes the digester contents with alkaline liquor to recover hydrolysate and steam condensate, preventing fiber loss and achieving high concentration of dissolved sugars, while maintaining controlled pH levels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If a separate washing stage is used to recover hydrolysate, then carbohydrate recovery is improved, but the process becomes time-consuming and produces a very dilute carbohydrate solution

Engineering Contradiction:
Improvecarbohydrate recoveryVSAvoidprocess time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The patent combines the washing stage with the cooking stage by introducing washing liquid into the digester during the cooking process. The washing liquid is circulated through the chips during the cooking phase, allowing simultaneous washing and cooking operations. This eliminates the need for a separate washing stage, reducing process time while maintaining carbohydrate recovery efficiency.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent implements continuous circulation of washing liquid through the chips during the cooking process. The washing liquid is pumped from the bottom of the digester, circulated through the chips via suction screens, and returned to the top, creating a continuous flow that maintains constant contact between the liquid and chips throughout the cooking phase.

Inventive Principle:
Principle #20Continuity of useful action

2Quantity of substance

If trickle-bed type down-flow recovery is used, then concentrated hydrolysate is obtained, but the recovery step is too slow and channeling occurs

Engineering Contradiction:
Improvehydrolysate concentrationVSAvoidrecovery speed
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

Instead of using a trickle-bed type down-flow recovery method, the patent inverts the approach by introducing washing liquid from the bottom of the digester and circulating it upward through the chips. This upward circulation through suction screens ensures even distribution of the washing liquid throughout the chip mass, preventing channeling while maintaining high recovery speed and concentrated hydrolysate.

Inventive Principle:
Principle #13The other way round (Inversion)

3Reliability

If traditional neutralization with alkaline neutralizing liquor is used, then hydrolysate is neutralized, but sulfur contamination occurs in the recovered hydrolysate

Engineering Contradiction:
ImproveneutralizationVSAvoidsulfur contamination
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and removes the harmful sulfur-containing components from the hydrolysate by using a washing liquid that does not contain sulfur. The washing liquid circulates through the chips, selectively removing carbohydrates while leaving sulfur-containing compounds behind in the solid phase. This extraction method produces sulfur-free recovered hydrolysate while maintaining effective neutralization.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process ensures even treatment of digester contents, improves energy efficiency, and produces high-grade pulp with essentially pure sulfur-free hydrolysate, enhancing the processing of carbohydrates and maintaining fiber quality.

Implementation Method 1

In the prehydrolysis stage carried out in a steam phase, direct steam is introduced to the chip column in the digester

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 2

neutralizing of the digester contents by displacing the washing liquid with alkaline liquor

Methodology Applied
Scientific EffectNeutralization:

Data Source

PatentEP2430233B1Method for producing pulp
Publication Date: 2013.05.08 METSO PAPER INC
  • EP2430233B1 patent drawingFigure 1

AI summary

A method for producing pulp is disclosed. More particularly, the invention concerns a displacement batch cooking process comprising a steam-phase prehydrolysis step, wherein the recovery of the by-products is improved. In the recovery step of the present invention, after the target P-factor in the prehydrolysis stage is reached, hot washing liquid is introduced into the digester from the bottom thereof. The washing liquid is circulated via the suction screens to the top and to the bottom of the digester until the prehydrolyzed chips are under the washing liquid. The hot washing liquid containing by-products is recovered from the digester and the digester contents are neutralized by displacing the washing liquid with alkaline liquor.