Diluted Microemulsions for Gas Well Water Block Removal

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Solution Overview

Problem

Diluted microemulsions used in gas wells often have high surface tensions, which hinder their effectiveness in treating gas wells by preventing the flow of hydrocarbon gas due to water blocks in rock formations.

Innovation Solution

Formulating microemulsions with specific solvents such as C6-C10 linear or branched alkane solvents, methylated cyclic alkane solvents, and methyl siloxane solvents that have low surface tensions, allowing for the reduction of capillary pressure and enhancement of hydrocarbon gas flow by injecting a diluted microemulsion with a surface tension of less than 28 mN/m into the wellbore.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If diluted microemulsions are used for treating gas wells, then they can potentially enhance hydrocarbon gas flow, but they have high surface tensions that prevent them from overcoming water blocks in rock formations

Engineering Contradiction:
Improvehydrocarbon gas flowVSAvoidsurface tension
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by modifying the surface tension of the microemulsion through selective solvent composition adjustments. Specifically, the microemulsion is formulated with solvents having low surface tensions (less than 34 mN/m at reservoir conditions) to achieve an overall surface tension less than 28 mN/m, enabling the fluid to overcome capillary pressure and water blocks in the reservoir, thereby resolving the contradiction between maintaining productivity enhancement and reducing surface tension effects.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If conventional solvents are used in microemulsions, then the formulation is simpler, but the surface tension remains high which reduces effectiveness in gas well treatment

Engineering Contradiction:
Improvemicroemulsion formulationVSAvoidsurface tension
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent employs composite materials by creating a microemulsion system that combines aqueous phase, surfactant, and specifically selected solvent components (C6-C10 linear or branched alkanes, methylated cyclic alkanes, and/or methyl siloxanes) to achieve synergistic effects. This composite formulation reduces surface tension to less than 28 mN/m while maintaining ease of manufacture through the use of commercially available solvent components that can be combined in a straightforward process.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these solvents in microemulsions reduces surface tension, allowing for increased hydrocarbon gas production by overcoming water blocks in rock formations, thereby enhancing gas flow and recovery from gas wells.

Implementation Method 1

The diluted microemulsion has a surface tension of less than 28 mN/m... The use of these solvents in microemulsions reduces surface tension

Methodology Applied
Scientific EffectSurface tension reduction: Surface Tension

Implementation Method 2

allowing for the reduction of capillary pressure and enhancement of hydrocarbon gas flow

Methodology Applied
Scientific EffectCapillary pressure reduction: Capillary Pressure

Data Source

PatentUS11180690B2Diluted microemulsions with low surface tensions
Publication Date: 2021.11.23 FLOTEK CHEMISTRY LLC
  • US11180690B2 patent drawing
  • US11180690B2 patent drawing
  • US11180690B2 patent drawing

AI summary

Compositions relating to microemulsions or diluted microemulsions for treating gas wells having wellbores and methods related to treating gas wells having wellbores using the same are generally provided. In some embodiments, the microemulsions or diluted microemulsions have an especially low surface tension at a gas well bottom hole temperature and pressure.