Dimer Fatty Acid-Polyether Reaction Product for Paint Adhesion

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Solution Overview

Problem

Existing multicoat paint systems face adhesion issues between basecoat and clearcoat films, particularly when exposed to weathering, leading to blisters and swelling, which compromises the durability and integrity of the paint system.

Innovation Solution

A dimer fatty acid-polyether reaction product is developed, with specific molecular weight ranges and molar ratios, to enhance adhesion between basecoat and clearcoat films, and between basecoat and the substrate, thereby minimizing blisters and swelling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional basecoat materials are used in multicoat paint systems, then the painting process can be completed, but adhesion problems occur between basecoat film and clearcoat film, especially after weathering exposure

Engineering Contradiction:
Improveadhesion between basecoat and clearcoatVSAvoidblisters and swelling after weathering
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the chemical composition parameters of the basecoat binder by incorporating specific reaction products (polyester polymers with controlled molecular weight, acid number, and hydroxyl content) to improve adhesion properties and resistance to weathering-induced blisters and swelling

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite binder system combining polyester polymers with specific additives and reaction products, where each component contributes different properties: the polyester provides backbone structure, while added reaction products enhance adhesion and weathering resistance, achieving superior overall performance

Inventive Principle:
Principle #40Composite materials

2Reliability

If basecoat materials with improved adhesion are developed, then coating integrity is enhanced, but the complexity of binder composition and manufacturing increases

Engineering Contradiction:
Improveadhesion between basecoat and substrateVSAvoidbinder composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies local quality by specifying particular regions of the binder molecule with specific properties: the polyester backbone provides structural integrity, while specific functional groups and reaction products are localized to provide adhesion enhancement, allowing each part of the binder to serve its optimal function without requiring complete redesign of the entire composition

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The reaction product significantly improves adhesion properties, reducing the incidence of blisters and swelling even after exposure to weathering, ensuring the longevity and integrity of the paint system.

Implementation Method 1

a dimer fatty acid-polyether-reaction product which is preparable by reacting (a) dimer fatty acids with (b) at least one polyether

Methodology Applied
Scientific EffectEsterification: Chemical Bonding

Data Source

PatentUS10501574B2Dimer fatty acid-polyether-reaction product and coating composition comprising the reaction product
Publication Date: 2019.12.10 BASF COATINGS GMBH
  • US10501574B2 patent drawing
  • US10501574B2 patent drawing
  • US10501574B2 patent drawing

AI summary

A dimer fatty acid-polyether-reaction product prepared by reacting a composition containing at least 80 wt % of one or more dimer fatty acids with at least one polyether of application formula (I) in a molar ratio of 0.7/2.3 to 1.6/1.7. The reaction product has a number-average molecular weight of 4800 to 40000 g/mol and an acid number of less than 10 mg KOH/g.