Direct Alcohol Fuel Cell with Oleophobic Filter for Microelectronics

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Solution Overview

Problem

Conventional batteries, such as zinc-air batteries, are inadequate for powering portable microelectronic devices like hearing aids due to limited energy density and non-rechargeable capabilities, requiring frequent replacement and lacking the flexibility for integration with microelectronic devices.

Innovation Solution

A direct alcohol fuel cell (DAFC) design featuring a proton exchange membrane (PEM) separating an anode and cathode section, with an inner housing that includes an anode collection element connected to an anode catalyst and a cathode collection element connected to a cathode catalyst, utilizing ventilation holes and an oleophobic filter to facilitate diffusive communication with fuel and oxidant, respectively, while minimizing volume and maximizing energy density.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional zinc-air batteries are used to power microelectronic devices, then the devices can operate with a compact power source, but the energy density is limited and the batteries require frequent replacement

Engineering Contradiction:
Improveenergy densityVSAvoidoperating time
Core Design Contradiction:
Quantity of substanceVSDuration of action of moving object

Solution Approach 1:

The patent changes the chemical composition parameters by using direct alcohol fuel cell chemistry instead of zinc-air battery chemistry. The fuel cell uses alcohol (methanol or ethanol) as fuel with oxygen from air, enabling higher energy density and rechargeable operation compared to conventional primary batteries.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The fuel cell employs composite material structures including proton exchange membrane (PEM), catalyst layers, gas diffusion layers, and collection elements. These composite structures enable efficient electrochemical conversion of alcohol fuel to electrical energy, achieving both high energy density and extended operating duration.

Inventive Principle:
Principle #40Composite materials

2Volume of moving object

If the fuel cell size is reduced for miniaturization, then the device can be integrated with microelectronic components, but the power output may be insufficient

Engineering Contradiction:
Improvefuel cell volumeVSAvoidpower output
Core Design Contradiction:
Volume of moving objectVSPower

Solution Approach 1:

The fuel cell is segmented into distinct functional layers (membrane, catalyst layers, gas diffusion layers, collection elements) that can be optimized independently. This segmentation allows miniaturization while maintaining efficient electrochemical reactions and adequate power output for microelectronic devices.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies local quality optimization by using catalyst-loaded porous layers and structured collection elements that maximize surface area and reaction efficiency within a compact volume. The local enhancement of reactive surfaces compensates for the reduced overall cell size, maintaining sufficient power output.

Inventive Principle:
Principle #3Local quality

3Strength

If thicker collection plates are used to collect high voltage, then the thermal capacity is sufficient, but the start-up characteristics at low temperature are adversely affected

Engineering Contradiction:
Improvethermal capacityVSAvoidstart-up speed
Core Design Contradiction:
StrengthVSSpeed

Solution Approach 1:

The patent uses thin-film collection elements instead of thick plates. The collection elements are sufficiently thin to provide rapid start-up at low temperatures while maintaining adequate electrical conductivity for voltage collection. The thin film structure reduces thermal mass, enabling faster response to temperature changes and quicker start-up.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The DAFC provides a higher energy density and recharging capability, enabling extended operating times for microelectronic devices by using pure methanol or ethanol, which can be replenished quickly, thus addressing the limitations of conventional batteries.

Implementation Method 1

due to the selective diffusion of protons across the PEM

Methodology Applied
Scientific EffectProton diffusion: Diffusion

Implementation Method 2

oxidation of the alcohol takes place at the anode

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

reduction of O2 takes place at the cathode

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 4

cathode catalyst, which cathode catalyst via the one or more ventilation holes is in diffusive communication with a gaseous oxidant

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS11699798B2Direct alcohol fuel cell
Publication Date: 2023.07.11 WIDEX AS
  • US11699798B2 patent drawing
  • US11699798B2 patent drawing

AI summary

A direct alcohol fuel cell having an inner housing, and a proton exchange membrane separating an anode section from a cathode section. The anode section contains an anode collection element electrically connected to an anode catalyst that is in diffusive communication with a fuel supply. The cathode section contains a cathode collection element having one or more ventilation holes is electrically connected to a cathode catalyst. An oleophobic filter and/or an anion-exchange membrane is provided, which cathode catalyst via the one or more ventilation holes and the oleophobic filter and/or the anion-exchange membrane is in diffusive communication with a gaseous oxidant. The inner housing has a bottom and walls extending from the bottom to contain the anode section, the PEM and the cathode section, the bottom and/or the walls having holes allowing fluid communication from a fuel supply to the anode section. The fuel cell is suited for microelectronic devices.