Discharge Ionization Detector with Dummy Electrode Noise Reduction

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Solution Overview

Problem

Conventional discharge ionization detectors face challenges with noise interference from electromagnetic sources and temperature fluctuations, which affect the baseline signal and reduce sensitivity and accuracy, especially in long-term measurements.

Innovation Solution

A discharge ionization current detector using a low-frequency barrier discharge with a plasma generation mechanism, an ion-collecting electrode, a dummy electrode, and differential detection means to minimize common mode noise and temperature drift, ensuring high sensitivity and accuracy by isolating the signal of interest from noise and baseline fluctuations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If a low-frequency barrier discharge is used to create stable plasma, then plasma stability is improved, but electromagnetic noise and temperature drift still affect detection accuracy

Engineering Contradiction:
Improveplasma stabilityVSAvoiddetection accuracy
Core Design Contradiction:
Stability of the object's compositionVSMeasurement precision

Solution Approach 1:

The patent introduces a dummy electrode that replicates the detection conditions of the ion-collecting electrode without being exposed to the sample gas. This copy electrode experiences the same electromagnetic noise and temperature drift, allowing these common-mode disturbances to be subtracted from the ion-collecting electrode signal, thereby improving detection accuracy while maintaining plasma stability

Inventive Principle:
Principle #26Copying

Solution Approach 2:

The patent uses differential detection as an intermediary mechanism between the plasma source and the final measurement. By comparing signals from both electrodes through differential amplification, the system mediates the effect of electromagnetic noise and temperature drift, allowing the true ionization signal to be extracted with higher precision

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If continuous operation is performed for long-term measurements, then productivity is improved, but noise and drift cause baseline fluctuation and decrease S/N ratio

Engineering Contradiction:
Improvecontinuous operation capabilityVSAvoidsignal-to-noise ratio
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The dummy electrode serves as a reference copy that continuously experiences the same environmental conditions during long-term operation. This enables continuous differential measurement that compensates for baseline drift and noise accumulation, maintaining high signal-to-noise ratio throughout extended measurement periods

Inventive Principle:
Principle #26Copying

Solution Approach 2:

The differential detection system provides continuous feedback about the baseline conditions through the dummy electrode signal. This feedback mechanism allows real-time compensation for drift and noise, enabling stable long-term operation with maintained measurement precision

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution effectively reduces noise and baseline fluctuations, enhancing the signal-to-noise ratio and maintaining high sensitivity and accuracy over extended measurement periods, thereby improving detection capabilities.

Implementation Method 1

a plasma generation means for generating a dielectric barrier discharge by a low-frequency AC electric field within a gas passage in which a plasma gas flows, so as to create plasma from the plasma gas by the dielectric barrier discharge

Methodology Applied
Scientific EffectDielectric barrier discharge: Electric Arc

Implementation Method 2

detecting an ion current originating from a sample component in the sample gas ionized by an action of light emitted from the plasma

Methodology Applied
Scientific EffectPhotoionization: Photoionisation

Data Source

PatentUS8829913B2Discharge ionization current detector
Publication Date: 2014.09.09 SHIMADZU CORP
  • US8829913B2 patent drawing
  • US8829913B2 patent drawing
  • US8829913B2 patent drawing

AI summary

A technique for reducing an electromagnetic noise entering an electrode or a drift of a signal due to a fluctuation in the ambient temperature is provided to improve the S/N ratio of a signal originating from a component of interest. A dummy electrode having the same structure as an ion-collecting electrode is provided within a lower gas passage at a position where dilution gas with no sample gas mixed therein flows. A differential amplifier is provided to perform differential detection between output A of a current amplifier connected to the ion-collecting electrode and output B of a current amplifier connected to the dummy electrode. The differential signal is free from a common mode noise or drift and hence accurately reflects the amount of the component of interest.