Dishwashing Detergent Composition for Plastic Stain Prevention

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Solution Overview

Problem

Existing automatic dishwashing detergents fail to effectively prevent the discoloration and staining of plastic items, particularly due to the transfer and redeposition of chromophoric soils like carotenes and curcumin, and traditional solutions like bleach are either ineffective or detrimental.

Innovation Solution

A dishwashing detergent composition comprising a water-soluble polyester, preferably an aromatic polyester, which is designed to prevent plastic discoloration during the washing process, suitable for monodose and autodosing applications.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional strong focus on cleaning and shine performance is maintained in ADW detergents, then cleaning and shine performance is improved, but plastic item protection and care deteriorates

Engineering Contradiction:
Improvecleaning and shine performanceVSAvoidplastic discoloration and staining
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The detergent composition provides different functional properties for different surfaces: hydrophilizing polymers for general surface care and shine, and specific water-soluble polyester compounds for plastic surface protection. This localized quality approach allows simultaneous optimization of cleaning performance and plastic care without compromise.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention uses composite detergent formulations combining multiple polymer types including water-soluble polyesters (PET, PBT, PTT), vinyl pyrrolidone copolymers, and other hydrophilizing agents. This composite approach creates synergistic effects that protect plastic surfaces while maintaining excellent cleaning and shine performance on all dishware types.

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If bleach is used as a traditional solution to remove red stains from surfaces, then stain removal is attempted, but plastic discoloration prevention deteriorates due to detrimental effects

Engineering Contradiction:
Improvestain removal capabilityVSAvoidplastic discoloration
Core Design Contradiction:
Object-generated harmful factorsVSObject-affected harmful factors

Solution Approach 1:

The invention transitions from oxidative stain removal (bleach) to a polymer-based prevention mechanism. Water-soluble polyesters change the surface parameters of plastic items by forming protective films that prevent chromophoric soil adhesion in the first place, eliminating the need for bleach and its detrimental effects on plastic.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Instead of using bleach to remove stains after they form (reacting to the problem), the water-soluble polyester polymers convert the approach by preventing stain formation altogether. The polymers create hydrophilic surfaces that actively repel hydrophobic chromophoric soils, turning the prevention task into a beneficial protective mechanism.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Object-affected harmful factors

If polymers are used for plastic surface care, then some protection is achieved, but satisfactory prevention of plastic discoloration is not achieved

Engineering Contradiction:
Improveplastic surface careVSAvoidplastic discoloration prevention
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention specifies particular water-soluble polyester parameters: molecular weights between 1,000-50,000 g/mol, specific chemical structures (PET, PBT, PTT), and concentrations of 0.1-5% in the detergent. These precise parameter changes transform generic polymer use into a reliable plastic protection system that effectively prevents discoloration.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Water-soluble polyester polymers act as intermediary substances between the plastic surface and chromophoric soils. They form a protective molecular layer that mediates the interaction, preventing direct contact between staining substances and plastic surfaces, thereby reliably preventing discoloration.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of a water-soluble polyester in the detergent composition significantly reduces plastic discoloration by inhibiting the migration of stains, providing superior protection compared to traditional formulations.

Implementation Method 1

WO04003124 discloses the use of low and high molar mass vinylpyrrolidone copolymers as a finishing aid for surface hydrophilization in an ADW composition

Methodology Applied
Scientific EffectHydrophilization: Hydrophile

Implementation Method 2

the strong attraction between the hydrophobic nature of staining substances and plastic surfaces (e.g., poly-propylene) is the driving force for this process that causes the migration of the stains into the plastic items

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20250361463A1A Dishwashing Detergent Composition, A Water-Soluble Container, and an Autodosing Automatic Dishwashing System
Publication Date: 2025.11.27 RECKITT BENCKISER FINISH BV
  • US20250361463A1 patent drawing
  • US20250361463A1 patent drawing
  • US20250361463A1 patent drawing

AI summary

The present invention is related to a dishwashing, preferably an automatic dishwashing, detergent composition; wherein the detergent composition comprises a water-soluble polyester.The present invention is also related to a dishwashing, preferably an automatic dishwashing, water-soluble container wherein said water-soluble container is made of a thermoformed water-soluble film comprising poly (vinyl alcohol) and wherein said water-soluble container is at least partially filled with such an inventive dishwashing, preferably an automatic dishwashing, detergent composition.