Disperse dye mixtures, their preparation and use

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Solution Overview

Problem

Existing disperse azo dyes fail to provide superior wash, contact, and sublimation fastness on hydrophobic textile materials like polyester and polyester-elastane, limiting their performance in dyeing and printing applications.

Innovation Solution

A mixture of specific disperse azo dyes with defined chemical structures, including those of formulas (I), (II), and (III), which are combined in specific ratios to enhance fastness properties, is used for dyeing hydrophobic materials, particularly polyester and polyester-elastane fabrics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If single disperse azo dyes are used for dyeing hydrophobic textile materials, then the dyeing process is simple, but the wash, contact, and sublimation fastness are insufficient

Engineering Contradiction:
Improvewash and contact fastnessVSAvoiddye mixture composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple disperse azo dyes with different chemical structures (formulae I, II, and III) into a single dye mixture. This merging of different dye components works synergistically to provide outstanding wash and contact fastness while maintaining good sublimation fastness, which cannot be achieved by single dyes alone.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention creates a composite dye system comprising dyes of formulae I, II, and III in specific weight ratios (1:0.5-2:0.5-2). This composite approach allows each dye component to contribute its strengths, resulting in a dye mixture with superior overall fastness properties compared to individual dyes.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If dye mixtures are used to improve fastness properties, then the service life of dyeings is extended, but the formulation complexity increases

Engineering Contradiction:
Improveservice life of dyeingsVSAvoiddye formulation
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent optimizes the weight ratios of the dye components (formulae I, II, and III) within specific ranges (1:0.5-2:0.5-2). By carefully adjusting these parameters, the invention achieves the best balance between fastness improvement and formulation simplicity, ensuring outstanding wash and contact fastness with good sublimation fastness.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If specific dye ratios are used to achieve level shades, then the uniformity of dyeing is improved, but the precision of formulation control is required

Engineering Contradiction:
Improveuniformity of shadeVSAvoidformulation control
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent assigns specific functional roles to each dye component in the mixture. Dyes of formula I, II, and III are selected to complement each other's properties, with each contributing specific characteristics that collectively achieve level shades and uniform dyeing distribution across the textile material.

Inventive Principle:
Principle #3Local quality

Data Source

PatentEP2663600B1Disperse dye mixtures, their preparation and use
Publication Date: 2017.09.20 DYSTAR COLOURS DISTRIBUTION GMBH
  • EP2663600B1 patent drawing
  • EP2663600B1 patent drawing
  • EP2663600B1 patent drawing

AI summary

The present invention relates to dye mixtures containing at least one dye of formula (I) and at least either a dye of formula (II) and/or at least one dye of formula (III) where R1-R15, n, o, X and D1-D3 are each as defined in claim 1. These dye mixtures are useful for dyeing or printing hydrophobic materials in particular.