Display Particles with Low-Reactive Copolymer for Whiteness and Viscosity

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Solution Overview

Problem

Existing display technologies using electrophoretic particles face challenges in achieving high refractive index and pure whiteness, particularly when particle size decreases, and struggle with viscosity issues in particle dispersion.

Innovation Solution

The development of particles for display that include a copolymer containing a reactive compound with a silicone or alkyl chain and a vinyl compound, where the content of the reactive compound is limited to 3.0% by weight or less, allowing for high refractive index and controlled viscosity in particle dispersion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If particles with high refractive index are used to improve display whiteness, then display quality improves, but particle dispersion viscosity increases

Engineering Contradiction:
Improvedisplay whitenessVSAvoiddispersion viscosity
Core Design Contradiction:
Illumination intensityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the particle coating by incorporating reactive compounds containing silicone chains or alkyl chains with specific molecular structures. This composition modification reduces the interfacial tension between particles and dispersion medium, thereby lowering dispersion viscosity while preserving the high refractive index property needed for display whiteness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite particle structures by coating electrophoretic particles with a copolymer layer containing reactive compounds (silicone/alkyl chain compounds) and vinyl compounds. This composite structure combines the high refractive index of the core particle with the low-viscosity properties of the polymer coating, simultaneously achieving improved display whiteness and reduced dispersion viscosity

Inventive Principle:
Principle #40Composite materials

2Length of moving object

If particle size is decreased to improve display resolution, then display quality improves, but refractive index and whiteness deteriorate

Engineering Contradiction:
Improveparticle sizeVSAvoiddisplay whiteness
Core Design Contradiction:
Length of moving objectVSIllumination intensity

Solution Approach 1:

The patent modifies the chemical composition of the particle coating by incorporating reactive compounds with specific molecular structures (silicone chains or alkyl chains). This composition parameter change enhances the optical properties of the particles, allowing small particles to maintain high refractive index and pure whiteness through improved light scattering efficiency at the molecular level

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If reactive compound content is increased to improve particle stability, then particle performance improves, but dispersion viscosity increases

Engineering Contradiction:
Improveparticle stabilityVSAvoiddispersion viscosity
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the content parameter of reactive compounds to 3.0% by weight or less, balancing particle stability requirements with dispersion viscosity control. This precise parameter optimization ensures sufficient particle stability while preventing excessive viscosity increase in the dispersion

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies a thin polymer coating layer (containing reactive compounds) on the particle surface rather than bulk modification. This localized application provides adequate surface stability for particle performance while minimizing the overall volume of high-viscosity material in the dispersion system

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in particles with high refractive index for improved display whiteness and reduced viscosity in particle dispersion, facilitating efficient and effective display applications.

Implementation Method 1

a copolymer that contains at least, as copolymer constituents, a reactive compound containing a silicone chain or an alkyl chain and a vinyl compound represented by Formula (1)

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

particles which are sealed between the substrates so as to be movable between the substrates in accordance with an electric field formed between the pair of substrates

Methodology Applied
Scientific EffectElectrophoresis: Electrophoresis

Data Source

PatentUS9030729B2Particles for display, particle dispersion for display, display medium, and display device
Publication Date: 2015.05.12 E INK CORP
  • US9030729B2 patent drawing
  • US9030729B2 patent drawing
  • US9030729B2 patent drawing

AI summary

Particles for display include a copolymer that contains at least, as copolymer constituents, a reactive compound containing a silicone chain or an alkyl chain and a vinyl compound represented by Formula (1), wherein a content of the reactive compound containing a silicone chain or an alkyl chain is 3.0% by weight or less with respect to the weight of the particles:ArH2C═CH2)n  Formula (1)wherein in Formula (1), Ar represents an unsubstituted aromatic ring or an aromatic ring that is substituted with an alkyl group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms, and n represents an integer from 1 to 4.