Display Protective Layer Combining Hard Coating and Anti-Reflection

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Solution Overview

Problem

Existing anti-reflective film processes for organic light-emitting devices are expensive, require multiple cleaning-coating-baking steps, and can cause staining and poor thickness uniformity, necessitating a more efficient and cost-effective alternative.

Innovation Solution

A display protective layer comprising a hard coating layer with an anti-reflective layer formed by a single coating process using inorganic particles with different refractive indices, where the surface of one type of particle is coated with a fluorine-containing moiety, allowing for a low specular component and improved hydrophobicity, thereby reducing reflections and enhancing layer uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If traditional anti-reflective film processes are used, then anti-reflective performance is achieved, but manufacturing cost increases and process complexity increases

Engineering Contradiction:
ImprovereflectionVSAvoidprocess complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent combines the anti-reflective layer and hard coating layer into a single integrated layer that performs both functions simultaneously. This merging eliminates the need for separate cleaning-coating-baking steps for each layer, reducing process complexity while maintaining anti-reflective performance through the specific particle composition (inorganic particles with refractive indices of 1.3-1.7 in a resin matrix).

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The anti-reflective hard coating layer is designed to perform multiple functions: anti-reflection, surface hardening, and scratch resistance. By incorporating inorganic particles with specific refractive indices into a resin-based hard coating matrix, the single layer achieves both optical (anti-reflective) and mechanical (hard coating) properties that traditionally required separate layers.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Object-affected harmful factors

If traditional anti-reflective film processes are used, then anti-reflective performance is achieved, but manufacturing cost increases

Engineering Contradiction:
ImprovereflectionVSAvoidmanufacturing cost
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent combines the anti-reflective layer and hard coating layer into a single integrated layer that performs both functions simultaneously. This merging eliminates the need for separate cleaning-coating-baking steps for each layer, reducing process complexity while maintaining anti-reflective performance through the specific particle composition (inorganic particles with refractive indices of 1.3-1.7 in a resin matrix).

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses a cost-effective formulation combining common resin materials (acrylate, polyester, or epoxy-based) with inorganic particles that can be produced economically. This approach replaces expensive traditional anti-reflective film processes with a more affordable sol-gel or dip-coating method using readily available materials.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Object-affected harmful factors

If traditional anti-reflective film processes are used, then anti-reflective performance is achieved, but staining occurs and thickness uniformity deteriorates

Engineering Contradiction:
ImprovereflectionVSAvoidthickness uniformity
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The patent controls the refractive index of the anti-reflective layer by selecting inorganic particles with specific refractive indices (1.3-1.7) and adjusting their concentration and size distribution. This parameter optimization ensures both effective anti-reflection and uniform light scattering, preventing staining while achieving consistent thickness across the display surface.

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If inorganic particles with different refractive indices are used, then anti-reflective performance improves, but manufacturing complexity increases

Engineering Contradiction:
ImprovereflectionVSAvoidmaterial complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent uses inorganic particles with different refractive indices (1.3-1.7) to create local variations in light scattering and reflection properties within the coating layer. This local quality variation optimizes anti-reflective performance at different depths and angles, while the particles are distributed uniformly to maintain overall manufacturing simplicity.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a low specular component and improved surface energy, reducing reflections and staining while being more economical and efficient than traditional methods, with a single coating step.

Implementation Method 1

a surface of the first inorganic particle may be coated with a fluorine-containing moiety

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Implementation Method 2

a surface energy of an upper portion of the anti-reflective layer may be less than or equal to about 25 dyne/cm

Methodology Applied
Scientific EffectSurface energy reduction: Surface Tension

Implementation Method 3

the anti-reflective layer may include a first inorganic particle having a first refractive index and a second inorganic particle having a second refractive index

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 4

an anti-reflective layer on the hard coating layer, wherein the anti-reflective layer may include a first inorganic particle having a first refractive index and a second inorganic particle having a second refractive index

Methodology Applied
Scientific EffectOptical interference: Interference

Implementation Method 5

The second refractive index may be greater than the first refractive index

Methodology Applied
Scientific EffectLight scattering: Scattering

Data Source

PatentUS20250318414A1Display protective layer and electronic apparatus comprising the same
Publication Date: 2025.10.09 SAMSUNG DISPLAY CO LTD
  • US20250318414A1 patent drawing
  • US20250318414A1 patent drawing
  • US20250318414A1 patent drawing

AI summary

A display protective layer includes a hard coating layer on a substrate, and an anti-reflective layer on the hard coating layer. The anti-reflective layer includes a first inorganic particle having a first refractive index and a second inorganic particle having a second refractive index, a surface of the first inorganic particle is coated with a fluorine-containing moiety, and the second refractive index is greater than the first refractive index.