Dissolvable Sheet Pore Structure via Aging and Anti-Gravity Drying

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Solution Overview

Problem

Flexible, porous dissolvable sheets with multiple layers face challenges in achieving a sufficient dissolution rate due to denser and less porous regions, particularly at the top surface, which impede water flow and overall dissolution.

Innovation Solution

Incorporating an aging step after aeration before drying, where the aerated pre-mixture is maintained for a specified time, and employing an anti-gravity heating direction during drying to enhance pore structures and dissolution profiles, specifically by allowing larger pore openings at the top surface.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If multiple layers of flexible dissolvable sheets are assembled into a unitary article, then the surfactant delivery capability is improved, but the dissolution rate significantly slows down

Engineering Contradiction:
Improvesurfactant delivery capabilityVSAvoiddissolution rate
Core Design Contradiction:
Quantity of substanceVSSpeed

Solution Approach 1:

The patent applies porous materials by creating a foam structure with controlled cell sizes during the drying process. The aerated pre-mixture is dried to form a porous network that allows water to penetrate through multiple layers simultaneously, maintaining fast dissolution rate while delivering sufficient surfactant quantity. The porous structure provides channels for water flow through the multi-layer assembly.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent transitions from a dense multi-layer structure to a three-dimensional porous foam structure. This dimensional change creates internal void space that allows water to access surfactants throughout the entire article volume simultaneously, rather than requiring sequential dissolution through each layer, thus maintaining fast dissolution rate while achieving sufficient surfactant delivery.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Speed

If porous sheets with open-celled foam structures are formed, then the dissolution rate is improved, but a denser and less porous region forms at the top surface

Engineering Contradiction:
Improvedissolution rateVSAvoidpore structure uniformity
Core Design Contradiction:
SpeedVSManufacturing precision

Solution Approach 1:

The patent applies equipotentiality by controlling the drying process to achieve uniform pore structure throughout the sheet. The drying conditions are optimized so that water evaporates uniformly from all regions, preventing the formation of a dense crust at the top surface. This results in consistent cell wall thickness and pore size distribution across the entire sheet, including the top surface region.

Inventive Principle:
Principle #12Equipotentiality

Solution Approach 2:

The patent applies parameter changes by carefully controlling drying temperature, humidity, and time parameters to prevent excessive water removal from the top surface. By adjusting these drying parameters, the process maintains adequate moisture during drying to preserve pore structure uniformity, resulting in consistent porosity throughout the sheet including the top surface region.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If the aerated pre-mixture is immediately dried after aeration, then the pore structure is maintained, but the dissolution profile is not optimized

Engineering Contradiction:
Improvepore structureVSAvoiddissolution profile
Core Design Contradiction:
Manufacturing precisionVSSpeed

Solution Approach 1:

The patent applies preliminary action by allowing the aerated pre-mixture to rest before drying. This preliminary resting period enables the air bubbles to stabilize and distribute uniformly throughout the pre-mixture, creating a more homogeneous foam structure. When drying subsequently occurs, this pre-stabilized structure results in better pore uniformity and optimized dissolution profile.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent applies continuity of useful action by maintaining the aerated state of the pre-mixture for an extended period before drying. The aeration effect is sustained continuously, allowing thorough bubble distribution and stabilization throughout the material. This continuous aeration maintains the beneficial pore-forming action until the drying process begins, optimizing the final pore structure and dissolution characteristics.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Results in a flexible, porous dissolvable sheet with improved pore structures and dissolution rates, characterized by larger pore openings at the top surface and more uniform pore size distribution across regions, facilitating faster water ingress and enhanced dissolution.

Implementation Method 1

aging the aerated wet pre-mixture for at least about 5 minute

Methodology Applied
Scientific EffectBubble coarsening: Ostwald Ripening

Implementation Method 2

drying the formed sheet for a drying time of from about 1 minute to about 60 minutes

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS12006410B2Flexible, porous, dissolvable solid sheet articles having large pores and method of making same
Publication Date: 2024.06.11 PROCTER & GAMBLE CO
  • US12006410B2 patent drawing
  • US12006410B2 patent drawing
  • US12006410B2 patent drawing

AI summary

This provides a flexible, porous, dissolvable solid sheet article having large pores on its top surface as well as a method of making the same.