Modelling of a distillation column with operating state changes

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Solution Overview

Problem

Current air separation installations operate statically, making it difficult to respond to fluctuating energy prices and varying demands, as existing methods fail to accurately predict the behavior of distillation columns under dynamic conditions, particularly with varying or absent feed fluid streams, affecting operability, load-changing rates, product quality, and energy efficiency.

Innovation Solution

A dynamic thermohydraulic simulation model for distillation columns with multiple stages, where the state is determined by pressure differences between stages, using a pressure-driven approach with coefficients of resistance and conductance values, allowing for dynamic operation and simulation of zero flows and flow reversals, enabling optimal control and energy management.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If air separation installations are operated statically with constant compressor power, then the system is simple to operate and stable, but it cannot respond to fluctuating energy prices and varying demands

Engineering Contradiction:
Improveresponse to fluctuating energy prices and varying demandsVSAvoiddynamic operation control system
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent applies dynamics by transitioning from static operation to dynamic operation where the distillation column can adapt to varying demands and energy prices. The system uses a dynamic model that calculates time-dependent states, allowing the column to respond flexibly to changing operating conditions while maintaining stability through controlled transitions.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent implements parameter changes by varying the compressor power and feed stream characteristics dynamically. The model incorporates time-dependent parameters such as variable feed composition, flow rates, and pressure conditions, enabling the system to optimize performance according to real-time energy prices and demand fluctuations.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If existing steady-state models are used for distillation columns, then the models are simple to calculate, but they fail to accurately predict behavior under dynamic conditions with varying or absent feed fluid streams

Engineering Contradiction:
Improveprediction accuracy under dynamic conditionsVSAvoiddynamic thermohydraulic simulation model
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent replaces traditional mechanical steady-state modeling approaches with a dynamic thermohydraulic simulation model. This substitution enables accurate prediction of column behavior under transient conditions, including start-up, shutdown, and varying feed conditions, by solving time-dependent mass and energy balance equations.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent applies preliminary action by developing a comprehensive dynamic model that anticipates and prepares for various operating scenarios. The model pre-calculates response characteristics for different feed conditions and energy price fluctuations, enabling operators to optimize performance before actual changes occur.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If the distillation column operates with varying feed fluid streams, then the system can adapt to different demands, but it becomes difficult to predict operability, maximum load-changing rates, and product quality

Engineering Contradiction:
Improveload-changing rateVSAvoidoperability prediction
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent implements feedback by using the dynamic model to continuously monitor and predict column response to feed variations. The model provides real-time information on operability limits, maximum load-changing rates, and product quality trends, enabling corrective actions to be taken before deviations occur.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent applies beforehand cushioning by using the dynamic model to identify and prepare for potential operability issues. The model predicts maximum load-changing rates and provides advance warning of potential problems, allowing operators to adjust conditions to maintain reliable operation.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for dynamic operation of air separation installations, optimizing energy use, responding to fluctuating energy prices, and improving the overall efficiency and product quality by simulating the behavior of distillation columns under varying conditions, including zero flows and flow reversals.

Implementation Method 1

both the gaseous and the liquid flows between the adjacent column stages are brought about by the pressure differences prevailing between the adjacent column stages

Methodology Applied
Scientific EffectPressure gradient: Pressure Gradient

Implementation Method 2

a distillation column having multiple column stages for separating a feed fluid stream into individual fluid components

Methodology Applied
Scientific EffectDistillation: Distillation

Implementation Method 3

determining a state of a distillation column having multiple column stages for separating a feed fluid stream into individual fluid components

Methodology Applied
Scientific EffectPhase equilibrium: Phase Change

Data Source

PatentUS11698225B2Modelling of a distillation column with operating state changes
Publication Date: 2023.07.11 LINDE AG
  • US11698225B2 patent drawing
  • US11698225B2 patent drawing
  • US11698225B2 patent drawing

AI summary

A method is provided for determining a state of a distillation column having multiple column stages for separating a feed fluid stream into individual fluid components. The state is determined by means of a model in a manner dependent on pressure differences prevailing between adjacent column stages. In the model, both gaseous and liquid flows between adjacent column stages are brought about by the pressure differences prevailing between adjacent column stages. A substance quantity flow characterizing gaseous flow between two column stages is given by {dot over (N)}V·RV=CV·ΔpV. A substance quantity flow characterizing liquid flow between two column stages is given by {dot over (N)}L·RL=CL·ΔpL. ΔpV,L is a total pressure difference between two adjacent column stages. RV,L is a coefficient of resistance between two adjacent column stages and CV,L is a conductance value of flow between two adjacent column stages.