Fluid-Tight DLC Coating for High-Pressure Sealing Surfaces

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional coatings for gate and seat components in high-pressure and high-temperature applications, such as oil and gas systems, face issues with friction, wear, corrosion, and fluid leakage due to inadequate lubricity, wear resistance, and fluid impermeability, leading to sticking, galling, and deformation.

Innovation Solution

A fully-dense, fluid-tight, low-friction coating system comprising a thermal spray-fused underlying layer of tungsten carbide-based material and self-fluxing alloy (SFA) without a polymeric or non-polymeric sealant, combined with a diamond-like carbon (DLC) layer, providing improved wear resistance, lubricity, and sealing properties at elevated temperatures and pressures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional polymeric lubricating coatings are applied to reduce friction, then lubricity is improved, but the coatings degrade over time at high temperatures and pressures, leading to increased friction and sticking

Engineering Contradiction:
ImprovelubricityVSAvoidcoating stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies a composite coating system consisting of a tungsten carbide-based wear-resistant layer combined with a diamond-like carbon (DLC) low-friction layer. This composite structure integrates the high hardness and wear resistance of tungsten carbide with the low coefficient of friction and thermal stability of DLC, achieving both improved lubricity and long-term reliability at high temperatures and pressures without degradation

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the material parameters by transitioning from organic polymeric coatings to inorganic coatings (tungsten carbide and DLC). This parameter change eliminates the temperature degradation issue inherent in polymers while maintaining low friction through the DLC layer's unique atomic structure and bonding characteristics

Inventive Principle:
Principle #35Parameter changes

2Strength

If wear-resistant coatings like WCCrCo are applied to improve wear resistance, then wear protection is improved, but the coatings exhibit porosity and gas leakage at high pressures and temperatures

Engineering Contradiction:
Improvewear resistanceVSAvoidfluid leakage
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent creates a composite coating where the tungsten carbide-based layer provides wear resistance and the DLC layer provides fluid tightness. The DLC layer acts as a seamless barrier that eliminates the porosity problem inherent in conventional sprayed coatings, preventing gas and fluid leakage while maintaining wear protection

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The DLC layer functions as a thin film barrier that conforms to the substrate surface and provides a continuous, non-porous seal. This thin film structure effectively blocks fluid and gas penetration pathways that would otherwise exist in porous wear-resistant coatings

Inventive Principle:
Principle #30Flexible shells and thin films

3Strength

If conventional thermal spray coatings are applied to protect sealing surfaces, then wear resistance is improved, but frictional forces increase at high pressures requiring larger actuators

Engineering Contradiction:
Improvewear resistanceVSAvoidfrictional force
Core Design Contradiction:
StrengthVSForce

Solution Approach 1:

The patent combines tungsten carbide-based material for wear resistance with diamond-like carbon for low friction. The DLC layer has an inherently low coefficient of friction that reduces the force required to move the gate, while the tungsten carbide layer maintains wear resistance, thereby reducing actuator size requirements

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent substitutes the friction-reducing mechanism by replacing conventional lubricating coatings with a DLC coating that provides low friction through its atomic structure and bonding characteristics rather than through lubrication films. This substitution eliminates the need for external lubricants and provides stable low-friction performance under high pressure

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating system achieves superior resistance to fluid leakage and maintains lubricity, wear resistance, and structural integrity at pressures up to 30,000 psi and temperatures up to 600°F, preventing sticking and galling, and ensuring a stable, impermeable seal over prolonged service life.

Implementation Method 1

a thermal spray-fused underlying layer on the substrate, said thermal spray-fused underlying layer produced from a blend comprising a tungsten carbide-based material and a self-fluxing alloy (SFA)

Methodology Applied
Scientific EffectThermal spray: Plasma Spray

Implementation Method 2

a low friction layer comprising a diamond-like carbon (DLC) material extending above said thermal spray-fused underlying layer

Methodology Applied
Scientific EffectDiamond-like carbon lubrication: Lubrication

Data Source

PatentEP3601633B1Fully dense, fluid tight and low friction coating systems for dynamically engaging load bearing surfaces for high pressure high temperature applications
Publication Date: 2023.02.22 PRAXAIR ST TECHNOLOGY INC
  • EP3601633B1 patent drawingFigure 1
  • EP3601633B1 patent drawingFigure 2~3
  • EP3601633B1 patent drawingFigure 4~5

AI summary

A fully-dense, fluid tight, low friction coating system is described that is characterized by fluid impermeability and a reduced coefficient of friction. The coating system includes a fully dense, fluid tight underlying layer; and a low friction layer. Unlike conventional materials requiring a sealant, the coating systems of the present invention achieves better fluid tightness and maintains said fluid tightness along one or more sealing surfaces at higher service temperatures and service pressures than previously attainable. The constituents of the fully-dense, fluid tight, low friction coating system are physically and chemically compatible so as to not adversely impact lubricity, wear resistance and corrosion resistance during the service life of a component coated with the fully-dense, fluid tight, low friction coating system.