Multi-layer DLC Coating Mitigates Metal Whiskers

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Solution Overview

Problem

Electronic components are prone to metal whiskering, which can lead to short circuits due to the formation of whisker-like metal projections, and existing conformal coatings are subject to oxidation and degradation, offering only temporary solutions.

Innovation Solution

A multi-layered coating system featuring a first layer of diamond-like carbon (DLC) to prevent metal whisker formation and a second layer of organic polymer to fill microfractures, with an optional third DLC layer for additional protection against oxidation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conformal coatings are applied to protect electronic components, then electrical insulation and environmental protection are improved, but the coatings themselves are subject to oxidation and degradation over time

Engineering Contradiction:
Improveelectrical insulationVSAvoidcoating longevity
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent applies a multi-layer composite coating system combining organic polymer conformal coating with inorganic barrier layers (such as silicon oxide, silicon nitride, or diamond-like carbon). This composite structure leverages the electrical insulation properties of the organic coating while the inorganic layers provide oxidation resistance and enhanced durability, solving the contradiction between providing electrical insulation and preventing coating degradation over time.

Inventive Principle:
Principle #40Composite materials

2Reliability

If metal components are used in electronic components, then conductivity and functionality are improved, but metal whiskering occurs leading to short circuits

Engineering Contradiction:
Improveelectrical conductivityVSAvoidmetal whisker formation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces an intermediary coating layer (such as nickel, gold, or the multi-layer conformal coating system) between the metal component and the environment. This intermediary layer prevents direct exposure of the metal to oxidizing conditions that cause whisker formation, while maintaining electrical conductivity through the coating system, thus resolving the contradiction between maintaining conductivity and preventing harmful whisker generation.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-generated harmful factors

If lead is added to tin solder to reduce tin whiskering, then metal whisker formation is mitigated, but toxicity increases

Engineering Contradiction:
Improvetin whisker formationVSAvoidtoxicity
Core Design Contradiction:
Object-generated harmful factorsVSObject-affected harmful factors

Solution Approach 1:

The patent uses the conformal coating system as an intermediary barrier between the tin solder and the environment, replacing the need for lead as a whisker-mitigating additive. The coating layer prevents oxidation of the tin, thereby eliminating whisker formation without introducing toxic substances, thus resolving the contradiction between preventing harmful whisker formation and avoiding toxicity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The DLC layer effectively mitigates metal whisker growth and provides long-term electrical insulation, while the polymer layer fills microcracks, enhancing the durability and longevity of electronic components by preventing oxidation and degradation.

Implementation Method 1

The first layer comprises diamond-like carbon (DLC) configured to mitigate metal whisker formation

Methodology Applied
Scientific EffectDiamond-like carbon coating: Diamond-like Carbon

Implementation Method 2

The conformal coating is configured to fill any microfractures that may form in the first layer

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 3

a second layer is applied on a top surface of the first layer. The second layer is a conformal coating comprising a second material configured to bind to the top surface of the first layer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS11729909B2Multi-layered diamond-like carbon coating for electronic components
Publication Date: 2023.08.15 HONEYWELL FEDERAL MANUFACTURING & TECHNOLOGIES LLC
  • US11729909B2 patent drawing
  • US11729909B2 patent drawing
  • US11729909B2 patent drawing

AI summary

A multi-layer coating on an outer surface of a substrate includes a first layer applied directly to the outer surface of the substrate. The first layer includes diamond-like carbon (DLC) configured to mitigate metal whisker formation. A second layer is applied on a top surface of the first layer. The second layer is a conformal coating that includes a second material configured to bind to the top surface of the first layer and fill any microfractures that may form in the first layer. Optionally, a third layer is applied on a top surface of the second layer and includes DLC configured to protect the second layer from oxidation and degradation.