Dual-Layer DLC Piston Ring Coating for Scoring Resistance

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Solution Overview

Problem

Existing piston ring coatings face challenges in achieving high hardness, low friction, and resistance to wear while maintaining compatibility with cylinder liners, particularly under high load and thin lubricant conditions, where the balance of sp3 and sp2 bonds and surface roughness is critical to prevent scoring and ensure durability.

Innovation Solution

A dual-layer hard amorphous carbon coating with a first layer having up to 45% sp3 bonds and a thickness of at least 10 micrometers, and a second layer with at least 55% sp3 bonds and a thickness of at least 3 micrometers, deposited using PVD, providing a roughness profile with low Rpk and high Rmr values to enhance contact and support between sliding surfaces.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a single-layer DLC coating with high sp3 bond content is applied to achieve high hardness, then hardness and wear resistance are improved, but the coating becomes too hard and brittle, causing scoring of the cylinder liner and increased risk of cracks

Engineering Contradiction:
ImprovehardnessVSAvoidscoring of cylinder liner
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The coating is divided into two distinct layers: a first layer with lower sp3 bond content (up to 45%) providing toughness and adhesion, and a second layer with higher sp3 bond content (at least 55%) providing hardness and wear resistance. This segmentation allows each layer to perform its specific function without the drawbacks of a homogeneous coating.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the coating have different chemical compositions and properties. The first layer near the substrate has lower sp3 content for flexibility, while the second outer layer has higher sp3 content for hardness. This local variation in quality optimizes both adhesion and surface performance.

Inventive Principle:
Principle #3Local quality

2Duration of action of stationary object

If the DLC coating thickness is increased to improve wear resistance, then durability is improved, but the surface roughness increases, reducing contact between sliding surfaces and worsening running-in conditions

Engineering Contradiction:
ImprovedurabilityVSAvoidsurface roughness
Core Design Contradiction:
Duration of action of stationary objectVSManufacturing precision

Solution Approach 1:

The thick coating (at least 10 micrometers total) is segmented into two layers with different sp3 bond contents. The second layer's higher sp3 content provides a denser, smoother surface structure that maintains low roughness even at greater thicknesses, while the first layer provides the bulk thickness for wear resistance.

Inventive Principle:
Principle #1Segmentation

3Strength

If the sp3 bond content is increased to improve hardness, then wear resistance is improved, but the internal stresses increase, generating cracks and reducing working life

Engineering Contradiction:
Improvewear resistanceVSAvoidworking life
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The coating is segmented into a stress-absorbing first layer with lower sp3 content and a hard protective second layer with higher sp3 content. The first layer acts as a stress buffer that prevents crack propagation into the substrate, while the second layer provides the desired wear resistance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first layer with lower sp3 bond content is deposited beforehand to create a cushioning layer that absorbs internal stresses. This prevents the subsequent high-sp3 second layer from generating cracks that would compromise the coating's reliability and working life.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

4Force

If thin layers of low viscosity lubricant oil are used to reduce friction, then friction is reduced, but the probability of direct contact between sliding components increases

Engineering Contradiction:
ImprovefrictionVSAvoidcontact between sliding components
Core Design Contradiction:
ForceVSReliability

Solution Approach 1:

The coating's surface properties are modified by controlling the sp3 bond content in the second layer, creating a surface with optimized roughness parameters (Rpk and Rmr) that enhances lubricant retention. This allows the thin lubricant film to maintain better contact and reduce the probability of direct metal-to-metal contact.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The dual-layer coating achieves high hardness between 25 GPa and 50 GPa, reducing friction and wear, improving the running-in condition, and minimizing the probability of scoring, while maintaining excellent durability and compatibility with cylinder liners.

Implementation Method 1

the application of layers of coating upon rings for engines working under high loads is realized through processes of deposition of vapor, especially physical vapor deposition (PVD)

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Data Source

PatentUS11466777B2Sliding element for an internal combustion engine
Publication Date: 2022.10.11 MAHLE INT GMBH
  • US11466777B2 patent drawing
  • US11466777B2 patent drawing
  • US11466777B2 patent drawing

AI summary

A sliding element for an internal combustion engine may include a base material having an annular external surface. The external surface may include a bonding layer, a first layer of coating, and a second layer of coating sequentially disposed thereon. The first layer of coating and the second layer of coating may include hard amorphous carbon (DLC) of a combined matrix having a plurality of sp3/sp2 bonds. The first layer of coating may include 45% sp3 bonds or less and may have a thickness of at least 10 micrometers. The second layer of coating may include at least 55% sp3 bonds and may have a thickness of at least 3 micrometers.