DMBPC Polycarbonate Ammonia and Scratch Resistance

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Traditional polycarbonates degrade when exposed to basic environments, such as ammonia, and are prone to scratching from abrasive materials, limiting their durability and effectiveness in various applications.

Innovation Solution

Polycarbonate articles are developed using Dimethyl bisphenol cyclohexane (DMBPC) as a monomer, which enhances scratch resistance and resistance to molecular weight degradation when exposed to ammonia, offering superior properties compared to traditional Bisphenol A (BPA) polycarbonates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional polycarbonate is used, then good dimensional stability and transparency are achieved, but the material degrades when exposed to basic environments like ammonia

Engineering Contradiction:
Improveresistance to ammonia degradationVSAvoidchemical stability in basic environment
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical composition parameters of the polycarbonate by incorporating DMBPC monomer units with specific structural characteristics (cyclohexane ring with dimethyl groups) that provide resistance to base-catalyzed degradation while maintaining the desired optical and mechanical properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite polycarbonate material combining DMBPC-derived structural units with traditional polycarbonate chains, achieving synergistic effects that provide both ammonia resistance and maintained mechanical performance

Inventive Principle:
Principle #40Composite materials

2Reliability

If traditional polycarbonate is used, then high impact strength and toughness are achieved, but the material scratches easily when exposed to abrasive materials

Engineering Contradiction:
Improvescratch and abrasion resistanceVSAvoidsurface hardness
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent modifies the surface properties and bulk composition of the polycarbonate by incorporating DMBPC units, which change the material's hardness and scratch resistance parameters while preserving the underlying toughness and impact strength

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP1937749B1Windows and other articles made from dmbpc polycarbonate homopolymer and copolymer
Publication Date: 2012.12.19 SABIC INNOVATIVE PLASTICS IP BV
  • EP1937749B1 patent drawingFigure 1
  • EP1937749B1 patent drawingFigure 2
  • EP1937749B1 patent drawingFigure 3

AI summary

Windows and other articles made from dimethyl bisphenol cyclohexane (DMBPC) polycarbonate exhibit enhanced scratch resistance properties and Mw degradation resistance properties as compared to traditional polycarbonates. Such windows and other articles made from DMBPC polycarbonate can be used in various applications including buildings, particularly in agricultural environments and in electronic devices.