Doped Diamond-Like Carbon Coating for Scale Inhibition

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Solution Overview

Problem

Existing methods for preventing scale-related fouling in industrial equipment, such as those used in the drilling industry, are costly and inefficient, requiring frequent well intervention and non-productive time, as they fail to effectively inhibit the deposition of inorganic or organic compounds in harsh environments.

Innovation Solution

A scale-inhibiting coating comprising a diamond-like carbon structure doped with a dopant at a concentration of 10 to 40 atomic percent, which is applied to surfaces to prevent scaling, enhance hydrophobicity and oleophobicity, and provide durability and abrasion resistance, while matching thermal expansion with the substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional scale prevention methods are used, then scale deposition is not effectively inhibited, but costly well intervention and non-productive time are required

Engineering Contradiction:
Improvescale prevention effectivenessVSAvoidnon-productive time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The scale-inhibiting coating is applied to the substrate surface before exposure to harsh environments, creating a pre-protective barrier that prevents scale deposition rather than requiring remediation after scaling occurs. This preliminary protective action eliminates the need for costly well intervention and non-productive time.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The diamond-like carbon coating with dopant acts as an intermediary layer between the substrate and the harsh environment, specifically between the substrate and scale-forming compounds. This intermediate coating prevents direct interaction between the substrate and scaling agents, effectively inhibiting scale deposition.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of repair

If remediation tools are used to remove scales, then scales can be removed, but costly well intervention and equipment downtime are required

Engineering Contradiction:
Improvescale removal capabilityVSAvoidequipment uptime
Core Design Contradiction:
Ease of repairVSLoss of time

Solution Approach 1:

The scale-inhibiting coating applies a counter-action in advance by creating a surface that actively repels scale-forming compounds. Instead of allowing scale to deposit and then removing it, the coating prevents deposition altogether through its unique surface properties, eliminating the need for remediation tools and well intervention.

Inventive Principle:
Principle #9Preliminary anti-action

Solution Approach 2:

The coating provides self-protective properties to the substrate, enabling it to resist scale deposition autonomously without requiring external remediation tools or intervention. The coating's inherent properties of low surface energy and chemical inertness allow it to self-repel scale-forming compounds.

Inventive Principle:
Principle #25Self-service

3Reliability

If frequent well intervention is performed for scale prevention, then scale buildup is addressed, but maintenance costs increase

Engineering Contradiction:
Improvescale controlVSAvoidmaintenance cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

Instead of relying on frequent partial interventions to address scale buildup, the invention applies a sufficient level of protection through the doped diamond-like carbon coating that provides long-lasting scale inhibition. The dopant concentration of 10-40 atomic percent ensures adequate protection, reducing the frequency of maintenance interventions.

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The invention changes the surface properties of the substrate by incorporating dopants at specific concentrations (10-40 atomic percent) in the diamond-like carbon coating. This parameter change in composition creates a surface with low surface energy and high chemical inertness, fundamentally altering the substrate's interaction with scale-forming compounds and providing long-term protection.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If standard coatings are used to protect surfaces, then some protection is provided, but durability and abrasion resistance are insufficient in harsh environments

Engineering Contradiction:
Improveprotection effectivenessVSAvoidabrasion resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention uses a composite material structure consisting of diamond-like carbon combined with specific dopants (such as fluorine, oxygen, or nitrogen) at controlled concentrations. This composite structure combines the hardness and wear resistance of diamond-like carbon with the chemical resistance and low surface energy provided by the dopants, creating a coating that withstands harsh environments.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention optimizes the dopant concentration parameter (10-40 atomic percent) to achieve the right balance between coating durability, chemical resistance, and scale inhibition. This parameter optimization ensures the coating maintains its mechanical properties while providing effective scale protection in harsh environments.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating significantly reduces scaling, increases hydrophobicity and oleophobicity, and maintains chemical and mechanical properties under harsh conditions, extending equipment uptime and reducing maintenance costs by effectively preventing the deposition of compounds like CaCO3, BaSO4, and asphaltene.

Implementation Method 1

enhance hydrophobicity and oleophobicity

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Implementation Method 2

enhance hydrophobicity and oleophobicity

Methodology Applied
Scientific EffectOleophobicity: Hydrophobe

Implementation Method 3

matching thermal expansion with the substrate

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Data Source

PatentUS9534476B2Scale-inhibiting coating
Publication Date: 2017.01.03 BAKER HUGHES CO
  • US9534476B2 patent drawing
  • US9534476B2 patent drawing
  • US9534476B2 patent drawing

AI summary

Disclosed is a coating for inhibiting the formation of scales on one or more surfaces of a component used in the production of subsurface fluids. The coating comprises a diamond-like carbon structure doped with a dopant, such as silicon, titanium, fluorine, oxygen, or chromium. The dopant comprises between about 10% and about 40% of the coating by atom.